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Why is nitric oxide paramagnetic in gaseous state but the solid obtained on cooling it is diamagnetic? - Chemistry

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प्रश्न

Why is nitric oxide paramagnetic in gaseous state but the solid obtained on cooling it is diamagnetic?

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उत्तर

In gaseous state \[\ce{NO2}\] exists as monomer which has one unpaired electron but in solid-state it dimerises to \[\ce{N2O4}\] so no unpaired electron is left hence solid form is diamagnetic.

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अध्याय 7: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ९६]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 7 The p-block Elements
Multiple Choice Questions (Type - I) | Q 43 | पृष्ठ ९६

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