मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Mention the factors that affect the rate of a chemical reaction.

Advertisements
Advertisements

प्रश्न

Mention the factors that affect the rate of a chemical reaction.

सविस्तर उत्तर
Advertisements

उत्तर

(i) Nature of the reactant: The rate of reaction depends on the nature of the reactant. For example, ionic molecules react more quickly than covalent ones.

(ii) State of reactants: Solid reactions are slower, liquid reactions are faster, and gas reactions are very quick.

(iii) Temperature: The rate of reaction is mainly affected by temperature. Every 10°C rise in temperature increases the reaction rate by 2-3 times.

`(r_(t + 10))/r_t` = 2 − 3

This ratio is called the temperature coefficient.

There are two reasons why the reaction rate increases with temperature.

  1. Increasing temperature raises the average kinetic energy of reactant molecules, increasing the rate of collisions.
  2. As the temperature rises, the number of molecules with threshold energy increases, resulting in more active molecules. As a result, the number of effective collisions grows. As a result, the reaction rate increases.

(iv) Concentration: The rate of reaction depends on the concentration of reactants.

Rate = k × Cn

Where,

n = order of reaction

C = concentration of reactant

(v) Catalyst: The presence of a catalyst changes the rate of the reaction. It lowers the activation energy by producing a chemical intermediate, lowering the potential energy barrier. Thus, the reaction rate increases.

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 3: Chemical Kinetics - Exercises [पृष्ठ ८५]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 3 Chemical Kinetics
Exercises | Q 3.5 | पृष्ठ ८५

संबंधित प्रश्‍न

In a first order reaction x → y, 40% of the given sample of compound remains unreacted in 45 minutes. Calculate rate constant of the reaction.


Write molecularity of the following reaction:

2NO(g)+O2(g)→2NO2(g)


For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

(iii) Write the unit of rate constant for this reaction.


For a reaction R ---> P, half-life (t1/2) is observed to be independent of the initial concentration of reactants. What is the order of reaction?


Write resonating structures of ozone.


Define the following terms:

Half-life period of reaction (t1/2).


Molecularity of a reaction _____________.


Which of the following statement is true for order of a reaction?


Consider a first order gas phase decomposition reaction given below :
\[\ce{A(g) -> B(g) + C(g)}\]
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of the system increased by x units and became ‘pt’ The rate constant k for the reaction is given as ______.


In a reaction if the concentration of reactant A is tripled, the rate of reaction becomes twenty seven times. What is the order of the reaction?


Why is the probability of reaction with molecularity higher than three very rare?


Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.

Reason: Reactant molecules undergo chemical change irrespective of their orientation during collision.


For a reaction R → p the concentration of reactant change from 0.03 m to 0.02 m in minute, calculate the average rate of the reaction using the unit of second.


The rate of a chemical reaction double for every 10° rise in temperature. If the temperature is raised. by 50°C, the rate of relation by about:-


For a reaction 1/2 A ⇒ 2B, rate of disappearance of A is related 't o the appearance of B by the expression:


At concentration of 0.1 and 0.2 mol L–1 the rates of deem position of a compound were found to be 0.18 and 0.72 mol L–1 m–1. What is the order of the reaction?


On heating compound (A) gives a gas (B) which is constituent of air. The gas when treated with H2 in the presence of catalyst gives another gas (C) which is basic in nature, (A) should not be ______.


A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×