मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules. Reason: Reactant molecules undergo chemical change irrespective of

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प्रश्न

Assertion: Rate constants determined from Arrhenius equation are fairly accurate for simple as well as complex molecules.

Reason: Reactant molecules undergo chemical change irrespective of their orientation during collision.

पर्याय

  • Both assertion and reason are correct and the reason is correct explanation of assertion.

  • Both assertion and reason are correct but reason does not explain assertion.

  • Assertion is correct but reason is incorrect.

  • Both assertion and reason are incorrect.

  • Assertion is incorrect but reason is correct.

MCQ
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उत्तर

Assertion is correct but reason is incorrect.

Explanation:

To Arrhenius equation `(k =Ae^((-Ea)/(RT)))`; it is found almost accurate for single as well as complex reaction.

However, orientation is essential for the reactant molecules participating in the reaction.

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पाठ 4: Chemical Kinetics - Exercises [पृष्ठ ५९]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 4 Chemical Kinetics
Exercises | Q V. 61. | पृष्ठ ५९

संबंधित प्रश्‍न

A reaction is second order in A and first order in B.

(i) Write the differential rate equation.

(ii) How is the rate affected on increasing the concentration of A three times?

(iii) How is the rate affected when the concentrations of both A and B are doubled?

 


For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :

t/s 0 30 60
[CH3COOCH3] / mol L–1 0.60 0.30 0.15

(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.

(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.

(Given log 2 = 0.3010, log 4 = 0.6021)


For a chemical reaction R → P, the variation in the concentration (R) vs. time (t) plot is given as:

(i) Predict the order of the reaction.

(ii) What is the slope of the curve?

(iii) Write the unit of rate constant for this reaction.


For the reaction:

\[\ce{2A + B -> A2B}\] 

the rate = k[A][B]2 with k = 2.0 × 10−6 mol−2 L2 s−1. Calculate the initial rate of the reaction when [A] = 0.1 mol L−1, [B] = 0.2 mol L−1. Calculate the rate of reaction after [A] is reduced to 0.06 mol L−1.


A reaction is first order in A and second order in B. Write the differential rate equation.


How does calcination differ from roasting?


Write resonating structures of ozone.


The decomposition of N2O5(g) at 320K according to the following equation follows first order reaction:

`N_2O_(5(g))->2NO_(2(g))+1/2O_(2(g))`

The initial concentration of N2O5(g) is 1.24 x 10-2 mol. L-1 and after 60 minutes 0.20x10-2 molL-1. Calculate the rate constant of the reaction at 320K.


Compounds ‘A’ and ‘B’ react according to the following chemical equation.
\[\ce{A(g) + 2B(g) -> 2C(g)}\]
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants constant and rates were measured as a function of initial concentration. Following results were obtained. Choose the correct option for the rate equations for this reaction.

Experiment Initial
concentration
of [A]/mol L–¹
Initial
concentration
of [B]/mol L–¹
Initial rate of
formation of
[C]/mol L–¹ s–¹
1. 0.30 0.30 0.10
2. 0.30 0.60 0.40
3. 0.60 0.30 0.20

The value of rate constant of a pseudo first order reaction ______.


For which type of reactions, order and molecularity have the same value?


For a reaction A + B → products, the rate law is given by: r = `K[A]^(1/2)`. What is the order of reaction?


For a reaction \[\ce{Cl2l(g) + 2No(g) -> 2NaCl(g)}\] the rate law is expressed as rate= K[Cl2] [No]2 what is the order of the reaction?


For a first order A → B, the reaction rate at reactant concentration of 0.01 m is found to be 2.0 × 10–5. The half-life period of reaction.


The conversion of molecules A to B follow second order kinetics. If concentration of A is increased to three times, how will it affect the rate of formation of B?


Read the following passage and answer the questions that follow:

The rate of reaction is concerned with decrease in the concentration of reactants or increase in the concentration of products per unit of time. It can be expressed as instantaneous rate at a particular instant of time and average rate over a large interval of time. A number of factors such as temperature, concentration of reactants, catalyst affect the rate of reaction. Mathematical representation of rate of a reaction is given by rate law:

Rate = k[A]x [B]y

x and y indicate how sensitive the rate is to change in concentration of A and B. Sum of x + y gives the overall order of a reaction.
When a sequence of elementary reactions gives us the products, the reaction is called complex reaction. Molecularity and order of an elementary reaction are same. Zero-order reactions are relatively uncommon but they occur under special conditions. All natural and artificial radioactive decay of unstable nuclei takes place by first-order kinetics.

  1. What is the effect of temperature on the rate constant of a reason?    [1]
  2. For a reaction \[\ce{A + B → Product}\], the rate law is given by, Rate = k[A]2 [B]1/2. What is the order of the reaction?    [1]
  3. How order and molecularity are different for complex reactions?    [1]
  4. A first-order reaction has a rate constant 2 × 10–3 s–1. How long will 6 g of this reactant take to reduce to 2 g?    [2]
    OR
    The half-life for radioactive decay of 14C is 6930 years. An archaeological artifact containing wood had only 75% of the 14C found in a living tree. Find the age of the sample.
    [log 4 = 0.6021, log 3 = 0.4771, log 2 = 0.3010, log 10 = 1]    [2]

On heating compound (A) gives a gas (B) which is constituent of air. The gas when treated with H2 in the presence of catalyst gives another gas (C) which is basic in nature, (A) should not be ______.


A drop of solution (volume 0.05 ml) contains 3.0 × 10-6 mole of H+. If the rate constant of disappearance of H+ is 1.0 × 107 mole l-1s-1. It would take for H+ in drop to disappear in ______ × 10-9s.


Which of the following statement is true?


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