Topics
Solid State
- Solid State
- Types of Solids
- Classification of Crystalline Solids
- Crystal Structure
- Cubic System
- Packing of Particles in Crystal Lattice
- Packing Efficiency
- Crystal Defects or Imperfections
- Properties of Solids: Electrical Properties
- Overview of Solid State
Solid State
- Introduction to Solid State
- Classification of Crystalline Solids
- Amorphous and Crystalline Solids
- Crystal Lattices and Unit Cells
- Calculations Involving Unit Cell Dimensions
- Close Packed Structures of Solids
- Efficiency of Packing in Body-centred Cubic Structures
- Close Packed Structures - Formula of a Compound and Number of Voids Filled
- Number of Atoms in a Unit Cell
- Imperfections in Solids - Introduction
- Properties of Solids: Magnetic Properties
- Band Theory of Metals
- Properties of Solids: Electrical Properties
- Applications of n-type and p-type Semiconductors
Solutions
- Introduction to Solutions
- Types of Solutions
- Capacity of Solution to Dissolve Solute
- Solubility
- Vapour Pressure of Solutions of Liquids in Liquids
- Colligative Properties of Nonelectrolyte Solutions
- Vapour Pressure Lowering
- Boiling Point Elevation
- Depression in Freezing Point
- Osmosis and Osmotic Pressure
- Colligative Properties of Electrolytes
- Overview of Solutions
Solutions and Colligative Properties
- Types of Solutions
- Expressing Concentration of Solutions
- Solubility of a Gas in a Liquid
- Solubility of a Solid in a Liquid
- Colligative Properties and Determination of Molar Mass - Introduction
- Relative Lowering of Vapour Pressure
- Depression of Freezing Point
- Osmosis and Osmotic Pressure
- Abnormal Molar Masses
- Elevation of Boiling Point
Ionic Equilibria
- Ionic Equilibria
- Types of Electrolyte
- Acids and Bases in Daily Life
- Ionization of Acids and Bases
- Autoionization of Water
- The pH Scale
- Hydrolysis of Salts
- Buffer Solutions
- Solubility product
- Common Ion Effect
- Overview of Ionic Equilibria
Chemical Thermodynamics and Energetic
- Chemical Thermodynamics and Energetic
- Concepts of System
- Types of Systems
- Surroundings
- Work, Heat, Energy, Extensive and Intensive Properties
- State Functions
- First Law of Thermodynamics
- Internal Energy and Enthalpy
- Hess’ Law of Constant Heat Summation
- Enthalpy of Bond Dissociation
- Combustion, Formation, Atomization, Sublimation
- Phase Transition
- Ionization and Solution
- Dilution Introduction of Entropy as a State Function
- Free Energy Change for Spontaneous and Non Spontaneous Processes
- Equilibrium Constant
- Second and Third Law of Thermodynamics
Electrochemistry
- Electrochemical Cells
- Conductance of Electrolytic Solutions - Introduction
- Variation of Conductivity and Molar Conductivity with Concentration
- Electrolytic Cells and Electrolysis - Introduction
- Primary Batteries
- Lead Accumulator
- Galvanic or Voltaic Cells - Introduction
- Nernst Equation - Introduction
- Relation Between Gibbs Energy Change and Emf of a Cell
- fuel cell
- Factors Affecting Corrosion
- Redox Reaction
Chemical Thermodynamics
- Chemical Thermodynamics
- Terms Used in Thermodynamics
- Nature of Heat and Work
- Expression for Pressure-volume (PV) Work
- Concept of Maximum Work
- Internal Energy (U)
- First Law of Thermodynamics
- Enthalpy (H)
- Enthalpies of Physical Transformations
- Thermochemistry
- Spontaneous (Irreversible) Process
- Overview of Chemical Thermodynamics
Chemical Kinetics
Electrochemistry
- Electrochemistry
- Electric Conduction
- Electrical Conductance of Solution
- Electrochemical Cells
- Electrolytic Cell
- Galvanic or Voltaic Cell
- Electrode Potential and Cell Potential
- Thermodynamics of Galvanic Cells
- Reference Electrodes
- Galvanic Cells Useful in Day-to-day Life
- Fuel Cells
- Electrochemical Series (Electromotive Series)
- Overview of Electrochemistry
Chemical Kinetics
- Chemical Kinetics
- Rate of Reactions
- Rate of Reaction and Reactant Concentration
- Molecularity of Elementary Reactions
- Integrated Rate Equations
- First Order Reactions
- Zero Order Reactions
- Half Life Period of a Reaction
- Pseudo First Order Reaction
- Integrated Rate Law for Gas Phase f Reactions
- Collision Theory of Bimolecular Reactions
- Temperature Dependence of Reaction Rates
- Effect of a Catalyst on the Rate of Reaction
- Overview of Chemical Kinetics
General Principles and Processes of Isolation of Elements
P-block Elements
Elements of Groups 16, 17 and 18
- Occurrence of Elements of Groups 16, 17 and 18
- Electronic Configuration of Elements of Group 16, 17 and 18
- Atomic and Physical Properties of Elements of Group 16, 17 and 18
- Anomalous Behaviour of Oxygen
- Anomalous Behaviour of Fluorine
- Chemical Properties of Elements of Groups 16, 17 and 18
- Oxoacids
- Oxygen and Compounds of Oxygen
- Chlorine
- Concept of Group 18 Elements
- Overview of Elements of Groups 16, 17 and 18
Group 15 Elements
Group 16 Elements
Group 17 Elements
- Concept of Group 17 Elements
- Anomalous Behaviour of Fluorine
- Compounds of Halogens
- Chlorine
- Hydrogen Chloride
- Interhalogen Compounds
- Oxoacids of Halogens
Group 18 Elements
Transition and Inner Transition Elements
- Transition and Inner Transition Elements
- Position in the Periodic Table of Transition and Inner Transition Elements
- Electronic Configuration of Transition and Inner Transition Elements
- Oxidation States of First Transition Series
- Physical Properties of First Transition Series
- Trends in Atomic Properties of the First Transition Series
- Preparation of Potassium Permanganate
- Chemical Properties of KMnO4
- Uses of KMnO4
- K2Cr2O7: Preparation of Potassium Dichromate
- Chemical Properties of K2Cr2O7
- Common Properties of d Block Elements
- Basic Principles of Metallurgy > Extraction of Metals
- Inner Transition (f-block) Elements: Lanthanoids and Actinoids
- Properties of f-block Elements
- Properties of Lanthanoids
- Applications of Lanthanoids
- The Actinoids
- Properties of Actinoids
- Applications of Actinoids
- Postactinoid Elements
- Overview of Transition and Inner Transition Elements
D and F Block Elements
D-block Elements
- General Indroduction
- Position in the Periodic Table - d-block Elements
- Electronic Configurations of the D-block Elements
- General Properties of the Transition Elements (D-block)
- Some Important Compounds of Transition Elements
F-block Elements
Coordination Compounds
- Introduction
- Nomenclature of Coordination Compounds - Formulas of Mononuclear Coordination Entities
- Nomenclature of Coordination Compounds - Naming of Mononuclear Coordination Compounds
- Importance of Coordination Compounds
- Definitions of Some Important Terms Pertaining to Coordination Compounds
- Colour in Coordination Compounds
- Magnetic Properties of Coordination Compounds
- Bonding in Coordination Compounds - Introduction
- Werner’s Theory of Coordination Compounds
- Valence Bond Theory (VBT)
- Crystal Field Theory (CFT)
- Stereoisomerism
- Structural Isomerism
- Importance of Coordination Compounds
Coordination Compounds
- Coordination Compounds
- Types of Ligands
- Terms Used in Coordination Chemistry
- Classification of Complexes
- IUPAC Nomenclature of Coordination Compounds
- Effective Atomic Number (EAN) Rule
- Isomerism in Coordination Compounds
- Stability of the Coordination Compounds
- Theories of Bonding in Complexes
- Applications of Coordination Compounds
- Overview of Coordination Compounds
Halogen Derivatives of Alkanes (And Arenes)
Halogen Derivatives
- Classification of Halogen Derivatives
- Nomenclature of Halogen Derivatives
- Methods of Preparation of Alkyl Halides
- Physical Properties
- Optical Isomerism in Halogen Derivatives
- Chemical Properties
- Reaction with Active Metals
- Uses and Environmental Effects of Some Polyhalogen Compounds
- Nomenclature
- Reactions of Haloalkanes - Elimination Reactions
- Overview of Halogen Derivatives
Haloalkanes
- Introduction of Haloalkanes and Haloarenes
- Nomenclature
- Nature of C-X Bond
- Physical Properties of Haloalkanes and Haloarenes
- Methods of Preparation of Haloalkanes and Haloarenes
- Reactions of Haloalkanes - Nucleophilic Substitution Reactions
- Reactions of Haloalkanes - Elimination Reactions
- R-s and D-l Configuration
Haloarenes
- Introduction of Haloalkanes and Haloarenes
- Nature of C-X Bond
- Reactions of Haloarenes - Nucleophilic Substitution
- Nucleophilic Substitution
- Electrophilic Substitution Reactions
- Reaction with Metals
- R-S and D-l Configurations
- Polyhalogen Compounds
Alcohols, Phenols and Ethers Alcohols
Alcohols, Phenols and Ethers
- Alcohols, Phenols and Ethers
- Classification of Alcohols, Phenols and Ethers
- Nomenclature
- Alcohols and Phenols
- Ethers
- Uses of Alcohols, Phenols and Ethers
- Overview of Alcohols, Phenols and Ethers
- Overview: Alcohols, Phenols and Ethers
Alcohols
Phenols
- Phenols
- Nomenclature
- Methods of Preparation
- Physical and Chemical Properties
- Acidic Nature of Phenol
- Electrophillic Substitution Reactions
- Uses of Phenols
Ethers
Aldehydes, Ketones and Carboxylic Acids
Aldehydes, Ketones and Carboxylic Acids
- Introduction of Aldehydes, Ketones and Carboxylic Acids
- Classification of Aldehydes, Ketones and Carboxylic Acids
- Nomenclature of Aldehydes, Ketones and Carboxylic Acids
- Preparation of Aldehydes and Ketones
- Preparation of Carboxylic Acids
- Physical Properties
- Polarity of Carbonyl Group
- Chemical Properties of Aldehydes and Ketones
- Chemical Properties of Carboxylic Acids
- Chemical Reactions of Aldehydes and Ketones - Reactions Due to α-hydrogen
- Overview: Aldehydes, Ketones and Carboxylic Acids
- Overview of Aldehydes, Ketones and Carboxylic Acids
Aldehydes and Ketones
- Introduction of Aldehydes, Ketones and Carboxylic Acids
- Nomenclature of Aldehydes and Ketones
- Nature of Carbonyl Group
- Preparation of Aldehydes and Ketones
- Physical Properties of Aldehydes and Ketones
- Chemical Reactions of Aldehydes and Ketones - Nucleophilic Addition Reactions
- Reactivity of Alpha Hydrogen in Aldehydes
- Uses of Aldehydes and Ketones
- Chemical Reactions of Aldehydes and Ketones - Other Reactions
Carboxylic Acids
- Carboxylic Acids
- Nomenclature of Carboxylic Acids
- Structure of the Carboxyl group
- Methods of Preparation of Carboxylic Acids
- Physical Properties of Carboxylic Acids
- Chemical Properties and Reactions of Carboxylic Acid
- Chemical Reactions of Carboxylic Acids - Reactions Involving Cleavege of O-H Bond
- Chemical Reactions of Carboxylic Acids - Reactions Involving Cleavege of C-OH Bond
- Chemical Reactions of Carboxylic Acids - Reactions Involving –COOH Group
- Chemical Reactions of Carboxylic Acids - Substitution Reactions in the Hydrocarbon Part
- Uses of Carboxylic Acids
Organic Compounds Containing Nitrogen
Amines
- Classification of Amines
- Nomenclature of Amines
- Preparation of Amines
- Physical Properties of Amines
- Basicity of Amines
- Chemical Properties of Amines
- Reactions of Arene Diazonium Salts
- Reaction with Arenesulfonyl Chloride
- Electrophilic Aromatic Substitution in Aromatic Amines
- Overview of Amines
Amines
- Introduction of Amines
- Nomenclature of Animes
- Classification of Amines
- Structure of Amines
- Physical Properties of Amines
- Uses of Amines
- Identification of Primary, Secondary and Tertiary Amines
- Secondary and Tertiary Amines
- Chemical Reactions of Amines - Carbylamine Reaction
- Chemical Reactions of Amines - Reaction with Nitrous Acid
- Chemical Reactions of Amines - Reaction with Arylsulphonyl Chloride
- Chemical Reactions of Amines - Electrophilic Substitution
- Preparation of Amines
Cyanides and Isocyanides
Diazonium Salts
Biomolecules
Biomolecules
- Principal Molecules of the Living World
- Biomolecules in the Cell > Carbohydrates
- Biomolecules in the Cell > Proteins
- Overview of Biomolecules
- Overview: Biomolecules
Carbohydrates
Proteins
- Introduction of Proteins
- Amino Acids
- Peptide
- Linkage
- Polypeptides
- Structure of Proteins
- Biomolecules in the Cell > Enzymes
- Lipids and Hormones
- Structure, Classification and Functions
Vitamins
- Introduction of Vitamins
- Classification of Vitamins
- Important Vitamins, Their Sources and Their Deficiency Diseases
Nucleic Acids
Polymers
- Introduction to Polymers
- Classification of Polymers Based on Source
- Types of Polymerisation Reactions - Addition Polymerisation or Chain Growth Polymerisation
- Types of Polymerisation Reactions - Copolymerisation
- Some Important Polymers
- Types of Polymerisation Reactions - Condensation Polymerisation Or Step Growth Polymerisation
- Nylon 6
- Nylon 66
- Types of Polymerisation Reactions - Rubber
- Biodegradable Polymers
- Preparation of Polytetrafluoroethene (Teflon)
- Preparation of Polyacrylonitrile
Introduction to Polymer Chemistry
- Introduction to Polymer Chemistry
- Classification of Polymers
- Some Important Polymers
- Molecular Mass and Degree of Polymerization of Polymers
- Biodegradable Polymers
- Commercially Important Polymers
- Preparation of Polytetrafluoroethene (Teflon)
- Overview of Introduction to Polymer Chemistry
Chemistry in Everyday Life
Green Chemistry and Nanochemistry
- Green Chemistry and Nanochemistry
- Principles of Green Chemistry
- The Role of Green Chemistry
- Introduction to Nanochemistry
- Characteristic Features of Nanoparticles
- Synthesis of Nanomaterials
- History of Nanotechnology
- Applications of Nanomaterials
- Nanoparticles and Nanotechnology
- Overview of Green Chemistry and Nanochemistry
Chemicals in Medicines
Chemicals in Food
Cleansing Agents
Definition: Biomolecules
The complex lifeless organic substances which form the basis of life and are responsible for the growth and maintenance of living systems are called biomolecules.
Definition: Metabolism
The sum total of all chemical reactions occurring in a living organism is called metabolism.
Definition: Metabolic pathway
The sequence of enzyme-catalysed reactions by which food is converted into body parts is called a metabolic pathway.
Definition: Carbohydrates
Polyhydroxy aldehydes or polyhydroxy ketones, or substances which on hydrolysis yield such compounds, are called carbohydrates.
Definition: Monosaccharides
Carbohydrates which cannot be hydrolysed to give simpler carbohydrates are called monosaccharides.
Definition: Oligosaccharides
Carbohydrates which on hydrolysis give a definite number (2–10) of monosaccharide units are called oligosaccharides.
Definition: Disaccharides
Carbohydrates which on hydrolysis give two monosaccharide units are called disaccharides.
Definition: Trisaccharides
Carbohydrates which on hydrolysis give three monosaccharide units are called trisaccharides.
Definition: Tetrasaccharides
Carbohydrates which on hydrolysis give four monosaccharide units are called tetrasaccharides.
Definition: Polysaccharides
Carbohydrates which on hydrolysis give a large number of monosaccharide units are called polysaccharides.
Definition: Reducing sugars
Carbohydrates capable of reducing Tollens’ reagent and Fehling’s solution are called reducing sugars.
Definition: Aldoses
Monosaccharides containing an aldehyde (–CHO) group are called aldoses.
Definition: Ketoses
Monosaccharides containing a keto (>C=O) group are called ketoses.
Definition: Heptoses
Monosaccharides containing seven carbon atoms are called heptoses.
Definition: Enantiomers
Two stereoisomers which are mirror images of each other and are non-superimposable are called enantiomers.
Definition: Mutarotation
The spontaneous change in optical rotation of an optically active compound in aqueous solution until equilibrium is reached is called mutarotation.
Definition: Anomers
A pair of stereoisomers which differ in configuration around the anomeric carbon atom are called anomers.
Definition: Glycosidic linkage
The linkage formed between two monosaccharide units through an oxygen atom by condensation is called a glycosidic linkage.
Definition: Starch
The principal storage polysaccharide of plants composed of α-glucose units is called starch.
Definition: Amylose
The linear water-soluble component of starch composed of α-1,4-glycosidic linked glucose units is called amylose.
Definition: Amylopectin
The branched water-insoluble component of starch composed of α-1,4 and α-1,6-glycosidic linked glucose units is called amylopectin.
Definition: Cellulose
The structural polysaccharide of plants composed of β-1,4-glycosidic linked glucose units is called cellulose.
Definition: Glycogen
The storage polysaccharide of animals found in liver and muscles is called glycogen.
Definition: Zwitter ion
The internal salt formed due to transfer of a proton from —COOH group to —NH₂ group in aqueous solution is called a zwitter ion.
Definition: Isoelectric point
The pH at which an amino acid exists as a neutral dipolar ion and does not migrate in an electric field is called the isoelectric point.
Definition: Peptides
The compounds obtained by condensation of two or more α-amino acids are called peptides.
Definition: Polypeptide
The peptide formed by condensation of many α-amino acids is called a polypeptide.
Definition: Peptide linkage
The —CO—NH— bond formed by condensation of two amino acid molecules is called a peptide bond or peptide linkage.
Definition: Proteins
The long polymers of amino acids linked together by peptide bonds and having high molecular mass are called proteins.
Definition: Enzymes
Globular proteins which act as biological catalysts in living systems and are produced by living cells are called enzymes.
Definition: Apoenzyme
The protein part of an enzyme without its cofactor is called an apoenzyme.
Definition: Holoenzyme
The complete catalytically active enzyme consisting of apoenzyme and cofactor is called a holoenzyme.
Definition: Hormones
Chemical substances secreted by ductless glands which regulate development and control activities of the body are called hormones.
Definition: Nucleic Acids
Biomolecules present in the nuclei of living cells which are responsible for storage and transmission of genetic information are called nucleic acids.
Definition: Nucleotide
The monomer unit of a nucleic acid is called a nucleotide.
Definition: Nucleoside
The base-sugar unit present in a nucleic acid chain is called a nucleoside.
Definition: Phosphodiester linkage
The linkage formed between nucleotides through phosphate group between 5′ and 3′ carbon atoms is called a phosphodiester linkage.
Definition: Chargaff’s rule
The rule stating that in DNA the amount of adenine equals thymine and the amount of cytosine equals guanine is called Chargaff’s rule.
Definition: Gene
The sequence of DNA that codes for a specific protein or polypeptide is called a gene.
Definition: Mutation
A chemical change in a DNA molecule which leads to the synthesis of proteins with a different amino acid sequence is called a mutation.
Definition: Mutant gene
The defective form of a gene resulting from mutation and capable of causing genetic disorders is called a mutant gene.
Key Points: Functions of Carbohydrates
- Carbohydrates are the main source of energy for living organisms and act as body fuels.
- Carbohydrates are stored as reserve food in plants as starch and in animals as glycogen.
- It provide structural support in plants by forming the cell wall (cellulose).
- Glucose formed from carbohydrates is oxidised in the body to release energy required for life processes.
Key Points: Properties of Enzymes
- The property by which an enzyme acts only on a specific substrate and catalyses only a particular type of reaction is called specificity of enzymes.
- The ability of enzymes to increase the rate of a reaction by many times compared to uncatalysed reactions is called catalytic efficiency of enzymes.
- The property by which a very small amount of enzyme is sufficient to catalyse a large amount of substrate because the enzyme is regenerated is called high catalytic power of enzymes.
- The condition at which the activity of an enzyme is maximum at a particular temperature and pH is called the optimum temperature and optimum pH of an enzyme.
Key Points: Classification of Hormones
| Type of Hormone | Description | Examples | Main Function |
|---|---|---|---|
| Steroid Hormones | Hormones which possess a steroid nucleus (four fused rings) and are derived from cholesterol. | Testosterone, Estrogen, Progesterone, Cortisone, Aldosterone | Control development of sex organs, metabolism, water and mineral balance. |
| Peptide Hormones | Hormones which consist of one or more polypeptide chains. | Insulin, Oxytocin, Vasopressin, Angiotensin II | Regulate blood glucose, control childbirth, water balance and blood pressure. |
| Amine Hormones | Hormones which are water-soluble amine compounds derived from amino acids. | Adrenaline, Thyroxine | Prepare body for emergency (adrenaline); control metabolism of carbohydrates, proteins and lipids (thyroxine). |
Key Points: Physiological Functions of Vitamins
- Vitamins are biological catalysts required in very small amounts to regulate various metabolic reactions in the body.
- Deficiency of one or more vitamins causes specific deficiency diseases, and this condition is called avitaminosis.
- Vitamins help in growth, metabolism, immunity, maintenance of tissues, blood formation and proper functioning of organs.
- Different vitamins have specific functions and sources, and their deficiency leads to characteristic diseases such as night blindness (Vitamin A), beriberi (Vitamin B₁), scurvy (Vitamin C) and rickets (Vitamin D).
