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The oxidation of toluene to benzaldehyde by chromyl chloride is called ______.
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The formula Co(NH3)5CO3Cl could represent a carbonate or a chloride. Write the structures and names of possible isomers.
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State Henry’s law and explain why are the tanks used by scuba divers filled with air diluted with helium (11.7% helium, 56.2% nitrogen and 32.1% oxygen)?
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Assume that argon exerts a partial pressure of 6 bar. Calculate the solubility of argon gas in water. (Given Henry’s law constant for argon dissolved in water, KH = 40 k bar)
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Write any two consequences of Lanthanoid Contraction.
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Convert the following:
Benzoic acid to Benzaldehyde.
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Explain the following reactions:
Stephan reaction
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Predict the reagent for carrying out the following transformations:
Benzoyl chloride to Benzaldehyde
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Write the IUPAC name of the following complex:
[CoBr2(en)2]+
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Arrange the following in increasing order of their boiling point:
C2H5OH, C2H5NH2, (C2H5)3N
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Solubility of gas in liquid decreases with increase in ______.
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The formula of the complex Iron (III) hexacyanidoferrate(II) is ______.
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In which of the following solvents, the \[\ce{C4H8NH3+X–}\] is soluble?
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Assertion (A): Strong oxidising agents oxidise toluene and its derivatives to benzoic acids.
Reason (R): It is possible to stop the oxidation of toluene at the aldehyde stage with suitable reagents.
Select the most appropriate answer from the options given below:
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Write the formula for the following coordination compound.
Bis (ethane-1,2-diamine) dihydroxidochromium (III) chloride
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An organic compound with molecular formula \[\ce{C7H7NO2}\] exists in three isomeric forms, the isomer ‘A’ has the highest melting point of the three. ‘A’ on reduction gives compound ‘B’ with molecular formula \[\ce{C7H9N}\]. ‘B’ on treatment with \[\ce{NaNO2/HCl}\] at 0-5° C to form compound ‘C’. On treating C with \[\ce{H3PO2}\], it gets converted to D with formula \[\ce{C7H8}\], which on further reaction with \[\ce{CrO2Cl2}\] followed by hydrolysis forms ‘E’ \[\ce{C7H6O}\]. Write the structure of compounds A to E. Write the chemical equations involved.
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Account for the following:
N-ethylbenzene sulphonyl amide is soluble in alkali.
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Account for the following:
Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCl.
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Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
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Write the name of the reaction, structure and IUPAC name of the product formed when:
CH3CH2CN reacts with stannous chloride in the presence of hydrochloric acid, followed by hydrolysis.
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