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Chemistry
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The oxidation of toluene to benzaldehyde by chromyl chloride is called ______.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

The formula Co(NH3)5CO3Cl could represent a carbonate or a chloride. Write the structures and names of possible isomers.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

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State Henry’s law and explain why are the tanks used by scuba divers filled with air diluted with helium (11.7% helium, 56.2% nitrogen and 32.1% oxygen)?

[1] Solutions
Chapter: [1] Solutions
Concept: undefined >> undefined

Assume that argon exerts a partial pressure of 6 bar. Calculate the solubility of argon gas in water. (Given Henry’s law constant for argon dissolved in water, KH = 40 k bar)

[1] Solutions
Chapter: [1] Solutions
Concept: undefined >> undefined

Write any two consequences of Lanthanoid Contraction.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
Concept: undefined >> undefined

Convert the following:

Benzoic acid to Benzaldehyde.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Explain the following reactions:

Stephan reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Predict the reagent for carrying out the following transformations:

Benzoyl chloride to Benzaldehyde

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the IUPAC name of the following complex:

[CoBr2(en)2]+

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

Arrange the following in increasing order of their boiling point:

C2H5OH, C2H5NH2, (C2H5)3N

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Solubility of gas in liquid decreases with increase in ______.

[1] Solutions
Chapter: [1] Solutions
Concept: undefined >> undefined

The formula of the complex Iron (III) hexacyanidoferrate(II) is ______.

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

In which of the following solvents, the \[\ce{C4H8NH3+X–}\] is soluble?

[1] Solutions
Chapter: [1] Solutions
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Assertion (A): Strong oxidising agents oxidise toluene and its derivatives to benzoic acids.

Reason (R): It is possible to stop the oxidation of toluene at the aldehyde stage with suitable reagents.

Select the most appropriate answer from the options given below:

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the formula for the following coordination compound.

Bis (ethane-1,2-diamine) dihydroxidochromium (III) chloride

[5] Coordination Compounds
Chapter: [5] Coordination Compounds
Concept: undefined >> undefined

An organic compound with molecular formula \[\ce{C7H7NO2}\] exists in three isomeric forms, the isomer ‘A’ has the highest melting point of the three. ‘A’ on reduction gives compound ‘B’ with molecular formula \[\ce{C7H9N}\]. ‘B’ on treatment with \[\ce{NaNO2/HCl}\] at 0-5° C to form compound ‘C’. On treating C with \[\ce{H3PO2}\], it gets converted to D with formula \[\ce{C7H8}\], which on further reaction with \[\ce{CrO2Cl2}\] followed by hydrolysis forms ‘E’ \[\ce{C7H6O}\]. Write the structure of compounds A to E. Write the chemical equations involved.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Account for the following:

N-ethylbenzene sulphonyl amide is soluble in alkali.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Account for the following:

Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCl.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Arrange the decreasing boiling point.

\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write the name of the reaction, structure and IUPAC name of the product formed when:

CH3CH2CN reacts with stannous chloride in the presence of hydrochloric acid, followed by hydrolysis.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined
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