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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Complete the synthesis by giving missing starting material, reagent or product. O CHO [Ag(NH3)2]+

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प्रश्न

Complete the synthesis by giving missing starting material, reagent or product.

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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५७]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.17 (v) | पृष्ठ २५७

संबंधित प्रश्न

Give a simple chemical test to distinguish between the following pair of compounds:

Ethanal and Propanal


A and B are two functional isomers of compound C3H6O.On heating with NaOH and I2, isomer B forms yellow precipitate of iodoform whereas isomer A does not form any precipitate. Write the formulae of A and B.


Give a simple chemical test to distinguish between the following pair of compounds :

CH3CH2CHO and CH3CH2COCH3


Give a simple chemical test to distinguish between the following pair of compounds:

Propanal and Propanone


Out of CH3CH2 – CO – CH2 – CH3 and CH3CH2 – CH2 – CO – CH3, which gives iodoform test?


How will you convert ethanal into the following compound?

But-2-enoic acid


An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.


Oxidation of ketones involves carbon-carbon bond cleavage. Name the products formed on oxidation of 2, 5-dimethylhexan-3-one.


Which sugar does not reduce Fehling's solution?


Acetone and acetaldehyde are differentiated by


Fehilng's test is positive for


Ammonical silver nitrate solution is called


A hydrocarbon (A) with molecular formula C5H10 on ozonolysis gives two products (B) and (C). Both (B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (B) give a silver mirror on reaction with Tollen’s reagent.

  1. Identify (A), (B) and (C).
  2. Write the reaction of B with Tollen’s reagent.
  3. Write the equation for iodoform test for C.
  4. Write down the equation for aldol condensation reaction of B and C.

An organic compound neither reacts with neutral ferric chloride solution nor with Fehling solution. It however, reacts with Grignard reagent and gives positive iodoform test. The compound is:


In Tollen's test for aldehyde, the overall number of electrons(s) transferred to the Tollen's reagent formula \[\ce{[Ag(NH3)2]+}\] per aldehyde group to form silver mirror is ______. (Round off to the nearest integer)


An organic compound 'A' with the molecular formula C4H8O2 undergoes acid hydrolysis to form two compounds 'B' and 'C'. Oxidation of 'C' with acidified potassium permanganate also produces 'B'. Sodium salt of 'B' on heating with soda lime gives methane.

  1. Identify 'A', 'B' and 'C'.
  2. Out of 'B' and 'C', which will have higher boiling point? Give reason.

You are given four organic compounds “A”, “B” , “C” and “D”. The compounds “A”, “B” and “C” form an orange-red precipitate with 2, 4 DNP reagent. Compounds “A” and “B” reduce Tollen’s reagent while compounds “C” and “D” do not. Both “B” and “C” give a yellow precipitate when heated with iodine in the presence of NaOH. Compound “D” gives brisk effervescence with sodium bicarbonate solution. Identify “A”, “B”, “C” and “D” given the number of carbon atoms in three of these carbon compounds is three while one has two carbon atoms. Give an explanation for our answer.


Fehling’s solution ‘A’ is ______.


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