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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Give a simple chemical test to distinguish between the following pair of compounds: Ethanal and Propanal

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प्रश्न

Give a simple chemical test to distinguish between the following pair of compounds:

Ethanal and Propanal

Give a chemical test to distinguish between propanal and ethanal.

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अंतर स्पष्ट करें
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उत्तर

Ethanal Propanal
Ethanal gives a yellow precipitate on heating with iodine in the presence of sodium hydroxide (positive Iodoform test). Propanal will not give any reaction on heating with iodine in the presence of sodium hydroxide (negative Iodoform test).

Ethanal gives the iodoform test, but propanal does not.

\[\ce{CH3CHO + \underset{Hypoiodite}{\underset{Sodium}{3NaOI}} ->[NaOH/I2][Heat] HCOONa + \underset{yellow ppt}{CHI3\downarrow} + 2NaOH}\]

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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ २५६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 8.13 (vii) | पृष्ठ २५६

संबंधित प्रश्न

Distinguish between: CH3COOH and HCOOH


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Give a simple chemical test to distinguish between the following pair of compounds:

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Complete the synthesis by giving missing starting material, reagent or product.


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  1. Identify (A), (B) and (C).
  2. Write the reaction of B with Tollen’s reagent.
  3. Write the equation for iodoform test for C.
  4. Write down the equation for aldol condensation reaction of B and C.

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An organic compound 'A' with molecular formula C5H8O2 is reduced to n-pentane with hydrazine followed by heating with NaOH and glycol. 'A' forms a dioxime with hydroxylamine and gives a positive iodoform and Tollen's test. Identify 'A' and give its reaction for iodoform and Tollen's test.


An organic compound 'A' with the molecular formula C4H8O2 undergoes acid hydrolysis to form two compounds 'B' and 'C'. Oxidation of 'C' with acidified potassium permanganate also produces 'B'. Sodium salt of 'B' on heating with soda lime gives methane.

  1. Identify 'A', 'B' and 'C'.
  2. Out of 'B' and 'C', which will have higher boiling point? Give reason.

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