Advertisements
Advertisements
प्रश्न
Oxidation of ketones involves carbon-carbon bond cleavage. Name the products formed on oxidation of 2, 5-dimethylhexan-3-one.
Advertisements
उत्तर
\[\begin{array}{cc}
\phantom{}\ce{CH3}\phantom{..}\ce{O}\phantom{..........}\ce{CH3}\phantom{..................}\ce{CH3}\phantom{...................}\ce{CH3}\phantom{.........................}\ce{O}\phantom{........................................................................}\\
\phantom{.}|\phantom{.....}||\phantom{...........}|\phantom{.....................}|\phantom{......................}|\phantom{.............................}||\phantom{........................................................................}\\
\phantom{}\ce{\underset{2, 5-Dimethylhexan-3-one}{CH3 - CH - C - CH2 - CH - CH3} ->[{[O]}] \underset{2-Methylpropanoic acid}{CH3 - CH - COOH} + \underset{3-Methylpropanoic acid}{CH3 - CH - CH2} - COOH + \underset{Propan-2-one}{CH3 - C - CH3} -> \underset{Ethanoic acid}{CH3COOH} + \underset{Methanoic acid}{HCOOH}\phantom{...........................................}}
\end{array}\]
APPEARS IN
संबंधित प्रश्न
A and B are two functional isomers of compound C3H6O.On heating with NaOH and I2, isomer B forms yellow precipitate of iodoform whereas isomer A does not form any precipitate. Write the formulae of A and B.
Give a simple chemical test to distinguish between the following pair of compounds:
Phenol and Benzoic acid
Give a simple chemical test to distinguish between the following pair of compounds:
Pentan-2-one and Pentan-3-one
An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.
Which of the following compounds will give butanone on oxidation with alkaline \[\ce{KMnO4}\] solution?
Which sugar does not reduce Fehling's solution?
Solvent used for dewaxing of petroleum products are
Fehilng's test is positive for
Ammonical silver nitrate solution is called
A hydrocarbon (A) with molecular formula C5H10 on ozonolysis gives two products (B) and (C). Both (B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (B) give a silver mirror on reaction with Tollen’s reagent.
- Identify (A), (B) and (C).
- Write the reaction of B with Tollen’s reagent.
- Write the equation for iodoform test for C.
- Write down the equation for aldol condensation reaction of B and C.
Write chemical test to distinguish between the following compounds:
Phenol and Benzoic acid
What is the composition of Fehling's reagent?
Which among the above compound/s does/do not form Silver mirror when treated with Tollen's reagent?
The major products formed in the following reaction sequence A and B are:
In Tollen's test for aldehyde, the overall number of electrons(s) transferred to the Tollen's reagent formula \[\ce{[Ag(NH3)2]+}\] per aldehyde group to form silver mirror is ______. (Round off to the nearest integer)
The reagent that can be used to distinguish acetophenone and benzophenone is ______.
