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Write the significance and limitations of octet rule.
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At 450 K, Kp= 2.0 × 1010/bar for the given reaction at equilibrium.
\[\ce{2SO2(g) + O2(g) ⇌2SO3 (g)}\]
What is Kc at this temperature?
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How will you convert benzene into m-nitrochlorobenzene?
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How will you convert benzene into p -nitrotoluene?
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How will you convert benzene into acetophenone?
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Addition of HBr to propene yields 2-bromopropane, while in the presence of benzoyl peroxide, the same reaction yields 1-bromopropane. Explain and give mechanism.
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Discuss the pattern of variation in the oxidation states of B to Tl.
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Discuss the pattern of variation in the oxidation states of C to Pb.
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Explain the difference in properties of diamond and graphite on the basis of their structures.
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Rationalise the given statement and give a chemical reaction:
Lead (II) chloride reacts with Cl2 to give PbCl4.
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Explain the following reaction.
Silicon is heated with methyl chloride at high temperature in the presence of copper.
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Explain why is there a phenomenal decrease in ionisation enthalpy from carbon to silicon?
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Write suitable chemical equations to show the nature of the following oxide.
Tl2O3
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Elements of group 14 ________.
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Discuss the general characteristics and gradation in properties of alkaline earth metals.
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Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?
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Which one of the alkaline earth metal carbonates is thermally the most stable?
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What do you understand by electron-rich compounds of hydrogen? Provide justification with a suitable example.
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What characteristics do you expect from an electron-deficient hydride with respect to its structure and chemical reactions?
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Do you expect the carbon hydrides of the type (CnH2n + 2) to act as ‘Lewis’ acid or base? Justify your answer.
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