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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Write the structure of the major organic product in the following reaction: CHA3CHA2Br+KCN→aq⋅ethanol - Chemistry

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प्रश्न

Write the structure of the major organic product in the following reaction:

\[\ce{CH3CH2Br + KCN ->[aq.ethanol]}\]

रासायनिक समीकरण/संरचनाएँ
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उत्तर

\[\ce{\underset{Bromoethane}{CH3CH2Br} + KCN ->[aq.ethanol][(nucleophilic substitution)] \underset{Propanenitrile}{CH3CH2CN} + KBr}\]

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अध्याय 6: Haloalkanes and Haloarenes - Exercises [पृष्ठ १९०]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 6 Haloalkanes and Haloarenes
Exercises | Q 6.14 (iv) | पृष्ठ १९०

संबंधित प्रश्न

Which would undergo SN1 reaction faster in the following pair and why?


Which compound in the following pair will react faster in SN2 reaction with OH?

(CH3)3CCl or CH3Cl


The treatment of alkyl chlorides with aqueous KOH leads to the formation of alcohols but in the presence of alcoholic KOH, alkenes are major products. Explain.


In a coordination entity of the type [PtCl2(en)2]2+ which isomer will show optical isomerism?


Which of the following compounds is optically active?


Which of the following is a chiral compound?


The correct order of increasing the reactivity of C–X bond towards nucleophile in following compounds.


    (I)


     (II)

(CH3)3CCl
    (III)

(CH3)2CHCl
    (IV)


Which of the following compound will undergo racemisation when reacts with aq. KOH?

(i)

(ii)

CH3CH2CH2Cl

(iii)

\[\begin{array}{cc}
\ce{CH3}\phantom{..}\\
|\phantom{....}\\
\ce{CH3-CH-CH2Cl}
\end{array}\]

(iv)

\[\begin{array}{cc}
\phantom{..}\ce{H}\\
\phantom{..}|\\
\ce{CH3-C-Cl}\\
\phantom{..}|\\
\phantom{.....}\ce{C2H5}
\end{array}\]


A primary alkyl halide would prefer to undergo ______.


Which of the statements are correct about above reaction?

(i) (a) and (e) both are nucleophiles.

(ii) In (c) carbon atom is sp3 hybridised.

(iii) In (c) carbon atom is sp2 hybridised.

(iv) (a) and (e) both are electrophiles.


Elimination reactions (especially β-elimination) are as common as the nucleophilic substitution reaction in case of alkyl halides. Specify the reagents used in both cases.


Among the following compounds I - IV, which one forms a yellow precipitate on reacting sequentially with (i) NaOH (ii) dil. HNO3 (iii) AgNO3?

I II III IV

Which of the following compounds will show retention in configuration on nucleophile substitution by OH ion?


The number of chiral carbons present in the molecule given below is ______.


The decreasing order of reactivity of the following compounds towards nucleophilic substitution (SN2) is ______.






Assertion (A) : Nucleophilic substitution of iodoethane is easier than chloroethane.

Reason (R) : Bond enthalpy of C-I bond is less than that of C-Cl bond.


Inversion of configuration occurs in ______.


 Acetic anhydride from acetic acid


Which of the following is halogen exchange reaction?


The compound that will undergo SN1 reaction with the fastest rate is:


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