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प्रश्न
When a metal of group 1 was dissolved in liquid ammonia, the following observations were obtained:
(i) Blue solution was obtained initially.
(ii) On concentrating the solution, blue colour changed to bronze colour.
How do you account for the blue colour of the solution? Give the name of the product formed on keeping the solution for some time.
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उत्तर
(i) The alkali metals dissolve in liquid ammonia and give a blue solution, which is conductive in nature. A solution of sodium in liquid ammonia at – 30°C conducts electricity. The ammoniated electrons are responsible for the blue color of the solution as they absorb energy in the visible region of light and impart blue color to the solution. Both the ammoniated cations and ammoniated electrons are responsible for the electrical conductivity of the solution.
\[\ce{Na + (x + y)NH3 -> [Na(NH3)x]^{+} + [e(NH3)y]-}\]
(ii) The blue color changes to bronze color in concentrated solution due to the formation of a cluster of metal ions. The standing blue solution liberates hydrogen gas with the formation of amide.
\[\ce{M^{+} + e- + NH3 -> MNH2 + 1/2 H2}\]
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संबंधित प्रश्न
Why are alkali metals not found in nature?
Explain why alkali and alkaline earth metals cannot be obtained by chemical reduction methods?
Why are potassium and cesium, rather than lithium used in photoelectric cells?
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
Which of the alkali metal is having least melting point?
Which one of the following alkali metals gives hydrated salts?
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to ______.
Which of the following elements does not form hydride by direct heating with dihydrogen?
Metallic elements are described by their standard electrode potential, fusion enthalpy, atomic size, etc. The alkali metals are characterised by which of the following properties?
(i) High boiling point.
(ii) High negative standard electrode potential.
(iii) High density.
(iv) Large atomic size.
Which of the following compounds are readily soluble in water?
(i) BeSO4
(ii) MgSO4
(iii) BaSO4
(iv) SrSO4
Choose the correct statements from the following.
(i) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(ii) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(iii) Beryllium exhibits coordination number more than four.
(iv) Beryllium oxide is purely acidic in nature.
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Application) |
| (a) Cs | (I) High temperature thermometer |
| (b) Ga | (II) Water repellent sprays |
| (c) B | (III) Photoelectric cells |
| (d) Si | (IV) Bullet proof vest |
Choose the most appropriate answer from the options given below:
A white precipitate was formed when BaCl2 was added to extract of an inorganic salt. Farther, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt is ______.
Nitrogen combines with metals to form ______.
Given below are two statements, one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Lithium salts are hydrated.
Reason (R) : Lithium has higher polarising power than other alkali metal group members.
In the light of the above statements, choose the most appropriate answer from the options given below :
