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प्रश्न
When a metal of group 1 was dissolved in liquid ammonia, the following observations were obtained:
(i) Blue solution was obtained initially.
(ii) On concentrating the solution, blue colour changed to bronze colour.
How do you account for the blue colour of the solution? Give the name of the product formed on keeping the solution for some time.
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उत्तर
(i) The alkali metals dissolve in liquid ammonia and give a blue solution, which is conductive in nature. A solution of sodium in liquid ammonia at – 30°C conducts electricity. The ammoniated electrons are responsible for the blue color of the solution as they absorb energy in the visible region of light and impart blue color to the solution. Both the ammoniated cations and ammoniated electrons are responsible for the electrical conductivity of the solution.
\[\ce{Na + (x + y)NH3 -> [Na(NH3)x]^{+} + [e(NH3)y]-}\]
(ii) The blue color changes to bronze color in concentrated solution due to the formation of a cluster of metal ions. The standing blue solution liberates hydrogen gas with the formation of amide.
\[\ce{M^{+} + e- + NH3 -> MNH2 + 1/2 H2}\]
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संबंधित प्रश्न
What are the common chemical features of alkali metals?
Why are alkali metals not found in nature?
Why are potassium and cesium, rather than lithium used in photoelectric cells?
When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.
Write a balanced equation for the reaction between Na2O and CO2.
Which of the alkali metal is having least melting point?
Which one of the following alkali metals gives hydrated salts?
For alkali metals, which one of the following trends is incorrect?
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to ______.
Metallic elements are described by their standard electrode potential, fusion enthalpy, atomic size, etc. The alkali metals are characterised by which of the following properties?
(i) High boiling point.
(ii) High negative standard electrode potential.
(iii) High density.
(iv) Large atomic size.
Choose the correct statements from the following.
(i) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(ii) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(iii) Beryllium exhibits coordination number more than four.
(iv) Beryllium oxide is purely acidic in nature.
When heated in air, the alkali metals form various oxides. Mention the oxides formed by Li, Na and K.
Write Lewis strucure of \[\ce{O^{-}2}\] ion and find out oxidation state of each oxygen atom? What is the average oxidation state of oxygen in this ion?
Ions of an element of group 1 participate in the transmission of nerve signals and transport of sugars and aminoacids into cells. This element imparts yellow colour to the flame in flame test and forms an oxide and a peroxide with oxygen. Identify the element and write chemical reaction to show the formation of its peroxide. Why does the element impart colour to the flame?
The valence shell electronic configuration of alkali metals is ______.
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Emitted light wavelength (nm)) |
| (a) Li | (I) 780.0 |
| (b) Na | (II) 455.5 |
| (c) Rb | (III) 670.8 |
| (d) Cs | (IV) 589.2 |
Choose the most appropriate answer from the options given below:
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Application) |
| (a) Cs | (I) High temperature thermometer |
| (b) Ga | (II) Water repellent sprays |
| (c) B | (III) Photoelectric cells |
| (d) Si | (IV) Bullet proof vest |
Choose the most appropriate answer from the options given below:
KO2 (potassium super oxide) is used in oxygen cylinders in space and submarines because it ______.
