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The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason.

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प्रश्न

The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason.

दीर्घउत्तर
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उत्तर

As the size of metal ions increases, the stability of peroxides and superoxides increases. Peroxide and superoxide ions combine with a large size of alkali metals. Lithium forms monoxide, sodium forms peroxide and potassium, rubidium and caesium forms superoxide.

\[\ce{Li + O2 -> Li2O}\]

\[\ce{Na + O2 -> Na2O2}\]

\[\ce{K + O2 -> KO2}\]

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पाठ 10: The s-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३२]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 10 The s-block Elements
Multiple Choice Questions (Type - I) | Q 49 | पृष्ठ १३२

संबंधित प्रश्‍न

Why are alkali metals not found in nature?


Explain why alkali and alkaline earth metals cannot be obtained by chemical reduction methods?


Why are potassium and cesium, rather than lithium used in photoelectric cells?


When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.


Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?


Which one of the following alkali metals gives hydrated salts?


The alkali metals are low melting. Which of the following alkali metal is expected to melt if the room temperature rises to 30°C?


Alkali metals react with water vigorously to form hydroxides and dihydrogen. Which of the following alkali metals reacts with water least vigorously?


The order of decreasing ionisation enthalpy in alkali metals is ______.


By adding gypsum to cement


Metallic elements are described by their standard electrode potential, fusion enthalpy, atomic size, etc. The alkali metals are characterised by which of the following properties?

(i) High boiling point.

(ii) High negative standard electrode potential.

(iii) High density.

(iv) Large atomic size.


Which of the following compounds are readily soluble in water?

(i) BeSO4

(ii) MgSO4

(iii) BaSO4

(iv) SrSO4 


Choose the correct statements from the following.

(i) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.

(ii) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.

(iii) Beryllium exhibits coordination number more than four.

(iv) Beryllium oxide is purely acidic in nature.


The valence shell electronic configuration of alkali metals is ______. 


The correct order of hydration enthapies of alkali metal ions is ______.


Nitrogen combines with metals to form ______.


Alkali metals are powerful reducing agents because ______.


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