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The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason. - Chemistry

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प्रश्न

The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason.

दीर्घउत्तर
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उत्तर

As the size of metal ions increases, the stability of peroxides and superoxides increases. Peroxide and superoxide ions combine with a large size of alkali metals. Lithium forms monoxide, sodium forms peroxide and potassium, rubidium and caesium forms superoxide.

\[\ce{Li + O2 -> Li2O}\]

\[\ce{Na + O2 -> Na2O2}\]

\[\ce{K + O2 -> KO2}\]

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अध्याय 10: The s-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३२]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
अध्याय 10 The s-block Elements
Multiple Choice Questions (Type - I) | Q 49 | पृष्ठ १३२

संबंधित प्रश्न

What are the common chemical features of alkali metals?


Explain why alkali and alkaline earth metals cannot be obtained by chemical reduction methods?


Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?


Which one of the following alkali metals gives hydrated salts?


The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to ______.


By adding gypsum to cement


Which of the following elements does not form hydride by direct heating with dihydrogen?


Metallic elements are described by their standard electrode potential, fusion enthalpy, atomic size, etc. The alkali metals are characterised by which of the following properties?

(i) High boiling point.

(ii) High negative standard electrode potential.

(iii) High density.

(iv) Large atomic size.


When heated in air, the alkali metals form various oxides. Mention the oxides formed by Li, Na and K.


Write Lewis strucure of \[\ce{O^{-}2}\] ion and find out oxidation state of each oxygen atom? What is the average oxidation state of oxygen in this ion?


The valence shell electronic configuration of alkali metals is ______. 


Match List-I with List-II.

List-I List-II
(Metal) (Emitted light wavelength (nm))
(a) Li (I) 780.0
(b) Na (II) 455.5
(c) Rb (III) 670.8
(d) Cs (IV) 589.2

Choose the most appropriate answer from the options given below:


The metal mainly used in devising photoelectric cells is ______.


KO2 (potassium super oxide) is used in oxygen cylinders in space and submarines because it ______.


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