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प्रश्न
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
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उत्तर
Lithium is the smallest in size among the alkali metals. Hence, Li+ ion can polarize water molecules more easily than other alkali metals. As a result, water molecules get attached to lithium salts as water of crystallization. Hence, lithium salts such as trihydrated lithium chloride (LiCl.3H2O) are commonly hydrated. As the size of the ions increases, their polarizing power decreases. Hence, other alkali metal ions usually form anhydrous salts.
संबंधित प्रश्न
What are the common chemical features of alkali metals?
Why are alkali metals not found in nature?
When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.
Which one of the following alkali metals gives hydrated salts?
For alkali metals, which one of the following trends is incorrect?
Which of the following statements is incorrect?
The alkali metals are low melting. Which of the following alkali metal is expected to melt if the room temperature rises to 30°C?
The order of decreasing ionisation enthalpy in alkali metals is ______.
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to ______.
In the synthesis of sodium carbonate, the recovery of ammonia is done by treating NH4Cl with Ca(OH)2. The by-product obtained in this process is ______.
Which of the following compounds are readily soluble in water?
(i) BeSO4
(ii) MgSO4
(iii) BaSO4
(iv) SrSO4
Choose the correct statements from the following.
(i) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(ii) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(iii) Beryllium exhibits coordination number more than four.
(iv) Beryllium oxide is purely acidic in nature.
When a metal of group 1 was dissolved in liquid ammonia, the following observations were obtained:
(i) Blue solution was obtained initially.
(ii) On concentrating the solution, blue colour changed to bronze colour.
How do you account for the blue colour of the solution? Give the name of the product formed on keeping the solution for some time.
The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason.
Ions of an element of group 1 participate in the transmission of nerve signals and transport of sugars and aminoacids into cells. This element imparts yellow colour to the flame in flame test and forms an oxide and a peroxide with oxygen. Identify the element and write chemical reaction to show the formation of its peroxide. Why does the element impart colour to the flame?
A white precipitate was formed when BaCl2 was added to extract of an inorganic salt. Farther, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt is ______.
The metal mainly used in devising photoelectric cells is ______.
Alkali metals are powerful reducing agents because ______.
