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प्रश्न
When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.
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उत्तर
When an alkali metal is dissolved in liquid ammonia, it results in the formation of a deep blue coloured solution.
\[\ce{M + (x + y) NH_3 -> M^+(NH_3)_x + e^{-1}(NH_3)_y}\]
The ammoniated electrons absorb energy corresponding to red region of visible light. Therefore, the transmitted light is blue in colour.
At a higher concentration (3 M), clusters of metal ions are formed. This causes the solution to attain a copper-bronze colour and a characteristic metallic lustre.
संबंधित प्रश्न
What are the common chemical features of alkali metals?
Why are alkali metals not found in nature?
Which of the alkali metal is having least melting point?
For alkali metals, which one of the following trends is incorrect?
Which of the following statements is incorrect?
The alkali metals are low melting. Which of the following alkali metal is expected to melt if the room temperature rises to 30°C?
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to ______.
In the synthesis of sodium carbonate, the recovery of ammonia is done by treating NH4Cl with Ca(OH)2. The by-product obtained in this process is ______.
Metallic elements are described by their standard electrode potential, fusion enthalpy, atomic size, etc. The alkali metals are characterised by which of the following properties?
(i) High boiling point.
(ii) High negative standard electrode potential.
(iii) High density.
(iv) Large atomic size.
Choose the correct statements from the following.
(i) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(ii) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(iii) Beryllium exhibits coordination number more than four.
(iv) Beryllium oxide is purely acidic in nature.
When heated in air, the alkali metals form various oxides. Mention the oxides formed by Li, Na and K.
Write Lewis strucure of \[\ce{O^{-}2}\] ion and find out oxidation state of each oxygen atom? What is the average oxidation state of oxygen in this ion?
Ions of an element of group 1 participate in the transmission of nerve signals and transport of sugars and aminoacids into cells. This element imparts yellow colour to the flame in flame test and forms an oxide and a peroxide with oxygen. Identify the element and write chemical reaction to show the formation of its peroxide. Why does the element impart colour to the flame?
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Emitted light wavelength (nm)) |
| (a) Li | (I) 780.0 |
| (b) Na | (II) 455.5 |
| (c) Rb | (III) 670.8 |
| (d) Cs | (IV) 589.2 |
Choose the most appropriate answer from the options given below:
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Application) |
| (a) Cs | (I) High temperature thermometer |
| (b) Ga | (II) Water repellent sprays |
| (c) B | (III) Photoelectric cells |
| (d) Si | (IV) Bullet proof vest |
Choose the most appropriate answer from the options given below:
The correct order of hydration enthapies of alkali metal ions is ______.
Nitrogen combines with metals to form ______.
The correct order of conductivity of ions in water is ______.
