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प्रश्न
When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.
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उत्तर
When an alkali metal is dissolved in liquid ammonia, it results in the formation of a deep blue coloured solution.
\[\ce{M + (x + y) NH_3 -> M^+(NH_3)_x + e^{-1}(NH_3)_y}\]
The ammoniated electrons absorb energy corresponding to red region of visible light. Therefore, the transmitted light is blue in colour.
At a higher concentration (3 M), clusters of metal ions are formed. This causes the solution to attain a copper-bronze colour and a characteristic metallic lustre.
संबंधित प्रश्न
Why are potassium and cesium, rather than lithium used in photoelectric cells?
Which one of the following alkali metals gives hydrated salts?
For alkali metals, which one of the following trends is incorrect?
Which of the following statements is incorrect?
Alkali metals react with water vigorously to form hydroxides and dihydrogen. Which of the following alkali metals reacts with water least vigorously?
Metals form basic hydroxides. Which of the following metal hydroxide is the least basic?
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to ______.
Which of the following elements does not form hydride by direct heating with dihydrogen?
Which of the following compounds are readily soluble in water?
(i) BeSO4
(ii) MgSO4
(iii) BaSO4
(iv) SrSO4
When heated in air, the alkali metals form various oxides. Mention the oxides formed by Li, Na and K.
When a metal of group 1 was dissolved in liquid ammonia, the following observations were obtained:
(i) Blue solution was obtained initially.
(ii) On concentrating the solution, blue colour changed to bronze colour.
How do you account for the blue colour of the solution? Give the name of the product formed on keeping the solution for some time.
The stability of peroxide and superoxide of alkali metals increase as we go down the group. Explain giving reason.
The ease of absorption of the hydrated alkali metals ions in an ion-exchange resin follows the order:
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Application) |
| (a) Cs | (I) High temperature thermometer |
| (b) Ga | (II) Water repellent sprays |
| (c) B | (III) Photoelectric cells |
| (d) Si | (IV) Bullet proof vest |
Choose the most appropriate answer from the options given below:
The metal mainly used in devising photoelectric cells is ______.
KO2 (potassium super oxide) is used in oxygen cylinders in space and submarines because it ______.
Which element from following is used as moderator in nuclear reactor?
