Advertisements
Advertisements
Question
When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.
Advertisements
Solution
When an alkali metal is dissolved in liquid ammonia, it results in the formation of a deep blue coloured solution.
\[\ce{M + (x + y) NH_3 -> M^+(NH_3)_x + e^{-1}(NH_3)_y}\]
The ammoniated electrons absorb energy corresponding to red region of visible light. Therefore, the transmitted light is blue in colour.
At a higher concentration (3 M), clusters of metal ions are formed. This causes the solution to attain a copper-bronze colour and a characteristic metallic lustre.
RELATED QUESTIONS
Why are alkali metals not found in nature?
Explain why alkali and alkaline earth metals cannot be obtained by chemical reduction methods?
The alkali metals are low melting. Which of the following alkali metal is expected to melt if the room temperature rises to 30°C?
Alkali metals react with water vigorously to form hydroxides and dihydrogen. Which of the following alkali metals reacts with water least vigorously?
The order of decreasing ionisation enthalpy in alkali metals is ______.
Which of the following elements does not form hydride by direct heating with dihydrogen?
Which of the following compounds are readily soluble in water?
(i) BeSO4
(ii) MgSO4
(iii) BaSO4
(iv) SrSO4
When a metal of group 1 was dissolved in liquid ammonia, the following observations were obtained:
(i) Blue solution was obtained initially.
(ii) On concentrating the solution, blue colour changed to bronze colour.
How do you account for the blue colour of the solution? Give the name of the product formed on keeping the solution for some time.
The valence shell electronic configuration of alkali metals is ______.
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Emitted light wavelength (nm)) |
| (a) Li | (I) 780.0 |
| (b) Na | (II) 455.5 |
| (c) Rb | (III) 670.8 |
| (d) Cs | (IV) 589.2 |
Choose the most appropriate answer from the options given below:
Match List-I with List-II.
| List-I | List-II |
| (Metal) | (Application) |
| (a) Cs | (I) High temperature thermometer |
| (b) Ga | (II) Water repellent sprays |
| (c) B | (III) Photoelectric cells |
| (d) Si | (IV) Bullet proof vest |
Choose the most appropriate answer from the options given below:
The correct order of hydration enthapies of alkali metal ions is ______.
Nitrogen combines with metals to form ______.
The correct order of conductivity of ions in water is ______.
KO2 (potassium super oxide) is used in oxygen cylinders in space and submarines because it ______.
Alkali metals are powerful reducing agents because ______.
Which element from following is used as moderator in nuclear reactor?
