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प्रश्न
Suggest the most important type of intermolecular attractive interaction in the following pair:
I2 and CCl4
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उत्तर
London dispersion forces are present as both molecules are non-polar.
संबंधित प्रश्न
How is the sign of ΔmixH related to positive deviations from Raoult’s law?
Suggest the most important type of intermolecular attractive interaction in the following pair.
Acetonitrile (CH3CN) and acetone (C3H6O)
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal, `P_"chloroform"` and `P_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:
| `bb(100 xx chi_"acetone")` | `bb(P_"acetone"//"mm Hg")` | `bb(P_"chloroform"//"mm Hg")` |
| 0 | 0 | 632.8 |
| 11.8 | 54.9 | 548.1 |
| 23.4 | 110.1 | 469.4 |
| 36.0 | 202.4 | 359.7 |
| 50.8 | 322.7 | 257.7 |
| 58.2 | 405.9 | 193.6 |
| 64.5 | 454.1 | 161.2 |
| 72.1 | 521.1 | 120.7 |
Plot this data also on the same graph paper. Indicate whether it has a positive or negative deviation from the ideal solution.
What type of intermolecular attractive interaction exists in the pair of methanol and acetone?
The molality of a solution containing 1.8 g of glucose dissolved in 250 g of water is
Two liquids X and Y on mixing gives a warm solution. The solution is ______.
Assertion: An ideal solution obeys Raoults Law.
Reason: In an ideal solution, solvent – solvent as well as solute – solute interactions are similar to solute-solvent interactions.
Which solution has the lower freezing point? 10 g of methanol (CH3OH) in 100g g of water (or) 20 g of ethanol (C2H5OH) in 200 g of water.
For ideal solution the enthalpy of mixing of the pure components to form the solution is ____________.
Which of the following condition is not satisfied by an ideal solution?
If two liquids A and B form minimum boiling azeotrope at some specific composition then ______.
Intermolecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?
(i) ∆mix H = zero
(ii) ∆mix V = zero
(iii) These will form minimum boiling azeotrope.
(iv) These will not form ideal solution.
Concentration terms such as mass percentage, ppm, mole fraction and molality are independent of temperature, however molarity is a function of temperature. Explain.
Assertion: Molarity of a solution in liquid state changes with temperature.
Reason: The volume of a solution changes with change in temperature.
Dissociation constant and molar conductance of an acetic acid solution are 1.78 × 10–5 mol L–1 and 48.15 S cm–2 mol–1 respectively. The conductivity of the solution is (considering molar conductance at infinite dilution is 390.5 S cm–2 mol–1)
How many times more hydrogen ions in a solution with a pH of 3 than in a solution with a pH of 6
If liquids A and B form an ideal solution, the ______.
What type of deviation from Roult’s Law is expected when phenol and aniline are mixed with each other? What change in the net volume of the mixture is expected? Graphically represent the deviation.
