Advertisements
Advertisements
प्रश्न
Assertion (A): The enthalpy of mixing Δmix H is equal to zero for an ideal solution.
Reason (R): For an ideal solution the interaction between solute and solvent molecules is stronger than the interactions between solute-solute or solvent-solvent molecules.
विकल्प
Both (A) and (R) are true and (R) is the correct explanation of (A).
Both (A) and (R) are true, but (R) is not the correct explanation of (A).
(A) is true, but (R) is false.
(A) is false, but (R) is true.
Advertisements
उत्तर
Both (A) and (R) are true and (R) is the correct explanation of (A).
Explanation:
For an ideal solution, the enthalpy of mixing and the volume of mixing are both zero. This is because the intermolecular forces of attraction between two solute particles and two solvent particles are the same as the forces of attraction between a solute particle and a solvent particle.
APPEARS IN
संबंधित प्रश्न
What role does the molecular interaction play in a solution of alcohol and water?
Suggest the most important type of intermolecular attractive interaction in the following pair.
Acetonitrile (CH3CN) and acetone (C3H6O)
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal, `P_"chloroform"` and `P_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:
| `bb(100 xx chi_"acetone")` | `bb(P_"acetone"//"mm Hg")` | `bb(P_"chloroform"//"mm Hg")` |
| 0 | 0 | 632.8 |
| 11.8 | 54.9 | 548.1 |
| 23.4 | 110.1 | 469.4 |
| 36.0 | 202.4 | 359.7 |
| 50.8 | 322.7 | 257.7 |
| 58.2 | 405.9 | 193.6 |
| 64.5 | 454.1 | 161.2 |
| 72.1 | 521.1 | 120.7 |
Plot this data also on the same graph paper. Indicate whether it has a positive or negative deviation from the ideal solution.
State Raoult law and obtain the expression for lowering of vapour pressure when the nonvolatile solute is dissolved Insolvent.
Explain the terms ideal and non-ideal solutions in the light of forces of interactions operating between molecules in liquid solutions.
Upon increase in pressure for dissociation N2O4 into NO2, equilibrium shift towards
How many times more hydrogen ions in a solution with a pH of 3 than in a solution with a pH of 6
1 mole of liquid A and 2 moles of liquid B make a solution having a total vapour pressure of 40 torr. The vapour pressure of pure A and pure B are 45 torr and 30 torr, respectively. The above solution ______.
Suggest the most important type of intermolecular attractive interaction in the following pair:
I2 and CCl4
Suggest the most important type of intermolecular attractive interaction in the following pair.
NaClO4 and water
