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Question
Suggest the most important type of intermolecular attractive interaction in the following pair:
I2 and CCl4
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Solution
Dispersion forces
RELATED QUESTIONS
Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane?
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot `p_"total"`, `p_"chloroform"` and `p_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:
| `bb(100 xx chi_"acetone")` | `bb(P_"acetone"//"mm Hg")` | `bb(p_"chloroform"//"mm Hg")` |
| 0 | 0 | 632.8 |
| 11.8 | 54.9 | 548.1 |
| 23.4 | 110.1 | 469.4 |
| 36 | 202.4 | 359.7 |
| 50.8 | 322.7 | 257.7 |
| 58.2 | 405.9 | 193.6 |
| 64.5 | 454.1 | 161.2 |
| 72.1 | 521.1 | 120.7 |
Plot this data also on the same graph paper. Indicate whether it has a positive or negative deviation from the ideal solution.
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
Ideal solutions obey ………. law and they …………. form azeotropic mixtures.
(Henry’s, aldol condensation, absence, do not, ohm, Raoult’s, increases, common ion effect, easily, three, solubility product, ohm-1, two, four, ohm-1, cm2, Cannizzaro, ohm-1 cm-1, zero, decreases, presence)
Two liquids X and Y on mixing gives a warm solution. The solution is ______.
The mass of a non – volatile solute (molar mass 80 g mol-1) should be dissolved in 92g of toluene to reduce its vapour pressure to 90% ______.
The observed depression in the freezing point of water for a particular solution is 0.093°C calculate the concentration of the solution in molality. Given that molal depression constant for water is 1.86 K Kg mol-1.
For ideal solution the enthalpy of mixing of the pure components to form the solution is ____________.
The rate at which a solid dissolves in liquid does not depend on ____________.
Which of the following condition is not satisfied by an ideal solution?
If two liquids A and B form minimum boiling azeotrope at some specific composition then ______.
Intermolecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?
(i) ∆mix H = zero
(ii) ∆mix V = zero
(iii) These will form minimum boiling azeotrope.
(iv) These will not form ideal solution.
What is “semi permeable membrane”?
Assertion: When a solution is separated from the pure solvent by a semipermeable membrane, the solvent molecules pass through it from pure solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration solution to a region of low concentration solution.
Upon increase in pressure for dissociation N2O4 into NO2, equilibrium shift towards
Dissociation constant and molar conductance of an acetic acid solution are 1.78 × 10–5 mol L–1 and 48.15 S cm–2 mol–1 respectively. The conductivity of the solution is (considering molar conductance at infinite dilution is 390.5 S cm–2 mol–1)
The pH of a solution of hydrochloric acid is 1.5. Calculate the concentration of the acid.
While titration dilute HCl solution with aqueous NaOH, which of the following will not be required?
Assertion (A): The enthalpy of mixing Δmix H is equal to zero for an ideal solution.
Reason (R): For an ideal solution the interaction between solute and solvent molecules is stronger than the interactions between solute-solute or solvent-solvent molecules.
1 mole of liquid A and 2 moles of liquid B make a solution having a total vapour pressure of 40 torr. The vapour pressure of pure A and pure B are 45 torr and 30 torr, respectively. The above solution ______.
Suggest the most important type of intermolecular attractive interaction in the following pair.
NaClO4 and water
