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प्रश्न
Suggest the most important type of intermolecular attractive interaction in the following pair.
NaClO4 and water
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उत्तर
Ion-dipole interactions, as water molecules are polar by nature, whereas NaClO4 becomes ionised in solution and provides Na+ and \[\ce{ClO^-_4}\] ions.
संबंधित प्रश्न
Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane?
Suggest the most important type of intermolecular attractive interaction in the following pair.
Acetonitrile (CH3CN) and acetone (C3H6O)
Vapour pressure of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal, `P_"chloroform"` and `P_"acetone"` as a function of `chi_"acetone"`. The experimental data observed for different compositions of mixtures is:
| `bb(100 xx chi_"acetone")` | `bb(P_"acetone"//"mm Hg")` | `bb(P_"chloroform"//"mm Hg")` |
| 0 | 0 | 632.8 |
| 11.8 | 54.9 | 548.1 |
| 23.4 | 110.1 | 469.4 |
| 36.0 | 202.4 | 359.7 |
| 50.8 | 322.7 | 257.7 |
| 58.2 | 405.9 | 193.6 |
| 64.5 | 454.1 | 161.2 |
| 72.1 | 521.1 | 120.7 |
Plot this data also on the same graph paper. Indicate whether it has a positive or negative deviation from the ideal solution.
Fill in the blanks by choosing the appropriate word/words from those given in the brackets:
Ideal solutions obey ………. law and they …………. form azeotropic mixtures.
(Henry’s, aldol condensation, absence, do not, ohm, Raoult’s, increases, common ion effect, easily, three, solubility product, ohm-1, two, four, ohm-1, cm2, Cannizzaro, ohm-1 cm-1, zero, decreases, presence)
The molality of a solution containing 1.8 g of glucose dissolved in 250 g of water is
Which of the following concentration terms is/are independent of temperature
The partial pressure of nitrogen in air is 0.76 atm and its Henry’s law constant is 7.6 × 104 atm at 300 K. What is the mole fraction of nitrogen gas in the solution obtained when air is bubbled through water at 300 K?
Which one of the following is incorrect for an ideal solution?
Which relationship is not correct?
Intermolecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?
(i) ∆mix H = zero
(ii) ∆mix V = zero
(iii) These will form minimum boiling azeotrope.
(iv) These will not form ideal solution.
Concentration terms such as mass percentage, ppm, mole fraction and molality are independent of temperature, however molarity is a function of temperature. Explain.
On increase in pressure for dissociation ofN2O4 into NO2, equilibrium shift towards
Which of the following gave the idea of a nucleus of the atom?
Lowering of vapour pressure of an aqueous solution of a non-volatile, non-electrolyte 1 molal aqueous solution at 100°C is ______.
While titration dilute HCl solution with aqueous NaOH, which of the following will not be required?
Assertion (A): The enthalpy of mixing Δmix H is equal to zero for an ideal solution.
Reason (R): For an ideal solution the interaction between solute and solvent molecules is stronger than the interactions between solute-solute or solvent-solvent molecules.
What type of deviation from Roult’s Law is expected when phenol and aniline are mixed with each other? What change in the net volume of the mixture is expected? Graphically represent the deviation.
