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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Show how the following compound can be converted to benzoic acid. Bromobenzene

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प्रश्न

Show how the following compound can be converted to benzoic acid.

Bromobenzene

रासायनिक समीकरण/संरचनाएँ
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उत्तर

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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Intext Questions [पृष्ठ २४८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Intext Questions | Q 8.7 (iii) | पृष्ठ २४८

संबंधित प्रश्न

Identify ‘A' and ‘B’ in the following reaction :

C6H5MgBr + C02 `(`> ‘A’   `(PCl_5)/()`> ‘B’

 


Predict the products of the following reactions:


Show how the following compound can be converted to benzoic acid.

Ethylbenzene


An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene. Write equations for the reactions involved.


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

Phenylacetic acid


How will you bring about the following conversion in not more than two steps?

Benazaldehyde to α-Hydroxyphenylacetic acid


What is the action of following reagents on glucose?
1. Bromine water
2. Hydroxylamine


Which is the most suitable reagent for the following conversion?

\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]


Through which of the following reactions number of carbon atoms can be increased in the chain?

(i) Grignard reaction

(ii) Cannizaro’s reaction

(iii) Aldol condensation

(iv) HVZ reaction


Match the reactions given in Column I with the suitable reagents given in Column II.

Column I
(Reactions)
Column II
(Reagents)
(i) Benzophenone Diphenylmethane (a) \[\ce{LiAlH4}\]
(ii) Benzaldehyde 1-Phenylethanol (b) \[\ce{DIBAL-H}\]
(iii) Cyclohexanone Cyclohexanol (c) \[\ce{Zn(Hg)/Conc. HCl}\]
(iv) Phenyl benzoate Benzaldehyde (d) \[\ce{CH3MgBr}\]

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.


Which of the following substance produced acetaldehyde on dry distillation?


Match List - I with List - II.

List - I List - II
(a) \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] (i) Hell-Volhard-Zelinsky reaction
(b)
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\
||\phantom{.................}\\
\ce{R - C - CH3 + NaOX ->}
\end{array}\]
(ii) Gattermann-Koch reaction
(c) \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] (iii) Haloform reaction
(d) \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] (iv) Esterification

Choose the correct answer from the options given below.


Alkaline hydrolysis of C4H8Cl2 gives a compound (A) which on heating with NaOH and I2 produces a yellow precipitate of CHI3. The compound (A) should be ______.


A compound 'X' with molecular formula C3H8O can be oxidised to a compound 'Y' with the molecular formula C3H6O2 'X' is most likely to be ______.


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