Advertisements
Advertisements
प्रश्न
Identify ‘A' and ‘B’ in the following reaction :
C6H5MgBr + C02 `(`> ‘A’ `(PCl_5)/()`> ‘B’
Advertisements
उत्तर
C6H5MgBr + CO2`"Dry ether"/("H"^+ /(H_2O))`> C6H5COOH `"PCl"/`> C6H5COCl
Phenyl Benzoic acid Benzoyl magnesium (A) chloride bromide (B)
APPEARS IN
संबंधित प्रश्न
How is carbolic acid prepared from chlorobenzene?
Show how the following compound can be converted to benzoic acid.
Acetophenone
Show how the following compound can be converted to benzoic acid.
Bromobenzene
Show how the following compound can be converted to benzoic acid.
Phenylethene (Styrene)
An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene. Write equations for the reactions involved.
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
m-Nitrobenzoic acid
How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.
p-Nitrobenzoic acid
How is methoxy benzene prepared from carbolic acid?
What is the action of following reagents on glucose?
1. Bromine water
2. Hydroxylamine
The functional group present in triacylglycerol is _______.
The reagent which does not react with both, acetone and benzaldehyde.
Which is the most suitable reagent for the following conversion?
\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]
Through which of the following reactions number of carbon atoms can be increased in the chain?
(i) Grignard reaction
(ii) Cannizaro’s reaction
(iii) Aldol condensation
(iv) HVZ reaction
Substitution of one alkyl group by replacing hydrogen of primary amines
Benzoic acid can be obtained by the oxidation of all of the following EXCEPT ______.
Match List - I with List - II.
| List - I | List - II | ||
| (a) | \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] |
(i) | Hell-Volhard-Zelinsky reaction |
| (b) |
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\ ||\phantom{.................}\\ \ce{R - C - CH3 + NaOX ->} \end{array}\] |
(ii) | Gattermann-Koch reaction |
| (c) | \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] | (iii) | Haloform reaction |
| (d) | \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] | (iv) | Esterification |
Choose the correct answer from the options given below.
Alkaline hydrolysis of C4H8Cl2 gives a compound (A) which on heating with NaOH and I2 produces a yellow precipitate of CHI3. The compound (A) should be ______.
Fill in the blanks by choosing the appropriate words from those given in the brackets:
[stable, low, aldehyde, unstable, 6, 4, ethane, Clemmensen’s, 2, 3, carboxylic acid, high, propane, Rosenmund's]
The primary alcohols are easily oxidised first into ______ and then into ______.
\[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\]