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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Show how the following compound can be converted to benzoic acid. Acetophenone - Chemistry

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प्रश्न

Show how the following compound can be converted to benzoic acid.

Acetophenone

रासायनिक समीकरण/संरचनाएँ
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उत्तर

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अध्याय 8: Aldehydes, Ketones and Carboxylic Acids - Intext Questions [पृष्ठ २४८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 8 Aldehydes, Ketones and Carboxylic Acids
Intext Questions | Q 8.7 (ii) | पृष्ठ २४८

संबंधित प्रश्न

Identify ‘A' and ‘B’ in the following reaction :

C6H5MgBr + C02 `(`> ‘A’   `(PCl_5)/()`> ‘B’

 


Predict the products of the following reactions:


Show how the following compound can be converted to benzoic acid.

Ethylbenzene


Show how the following compound can be converted to benzoic acid.

Bromobenzene


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

Methyl benzoate


How will you bring about the following conversion in not more than two steps?

Benazaldehyde to α-Hydroxyphenylacetic acid


Complete the synthesis by giving missing starting material, reagent or product.


How is methoxy benzene prepared from carbolic acid?


Name the reagents used in the following reactions:


The reagent which does not react with both, acetone and benzaldehyde.


Which is the most suitable reagent for the following conversion?

\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]


Through which of the following reactions number of carbon atoms can be increased in the chain?

(i) Grignard reaction

(ii) Cannizaro’s reaction

(iii) Aldol condensation

(iv) HVZ reaction


Match the reactions given in Column I with the suitable reagents given in Column II.

Column I
(Reactions)
Column II
(Reagents)
(i) Benzophenone Diphenylmethane (a) \[\ce{LiAlH4}\]
(ii) Benzaldehyde 1-Phenylethanol (b) \[\ce{DIBAL-H}\]
(iii) Cyclohexanone Cyclohexanol (c) \[\ce{Zn(Hg)/Conc. HCl}\]
(iv) Phenyl benzoate Benzaldehyde (d) \[\ce{CH3MgBr}\]

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.


The end product Y in the sequence of reaction:

\[\ce{RX ->[CN^-] X ->[NaOH] Y}\] is:


Alkaline hydrolysis of C4H8Cl2 gives a compound (A) which on heating with NaOH and I2 produces a yellow precipitate of CHI3. The compound (A) should be ______.


A compound 'X' with molecular formula C3H8O can be oxidised to a compound 'Y' with the molecular formula C3H6O2 'X' is most likely to be ______.


Hex-4-ene-2-ol on treatment with PCC gives 'A'. 'A' on reaction with sodium hypoiodite gives 'B', which on further heating with soda lime gives 'C. The compound 'C' is ______.


Fill in the blanks by choosing the appropriate words from those given in the brackets:

[stable, low, aldehyde, unstable, 6, 4, ethane, Clemmensen’s, 2, 3, carboxylic acid, high, propane, Rosenmund's]

The primary alcohols are easily oxidised first into ______ and then into ______.


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