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Mention the factors that affect the rate of a chemical reaction. - Chemistry

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प्रश्न

Mention the factors that affect the rate of a chemical reaction.

संक्षेप में उत्तर
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उत्तर

The factors that affect the rate of a reaction are as follows:

(i) Nature of the reactant - The rate of reaction depends on the nature of the reactant. For instance, ionic molecules react more quickly than covalent ones.

(ii) State of reactants - Solid reactions are slower, liquid reactions are faster, and gas reactions are very quick.

(iii) Temperature - The rate of reaction is mainly affected by temperature. Every 10°C rise in temperature leads to an increased rate of reaction by 2-3 times.

`(r_(t + 10))/r_t` = 2 − 3

This ratio is called the temperature coefficient. 

There are two reasons why the rate of reaction increases with increasing temperature.

  1. Increasing temperature raises the average kinetic energy of reactant molecules, increasing the rate of collisions.
  2. As temperature rises, the number of molecules with threshold energy increases, resulting in more active molecules. As a result, the number of effective collisions grows. As a result, the rate of reaction rises.

(iv) Concentration - The rate of reaction depends on the concentration of reactants.

Rate = k × Cn, where n = order of reaction, C = concentration of reactant.

(v) Catalyst The presence of a catalyst changes the rate of the reaction. It lowers the activation energy by producing a chemical intermediate, lowering the potential energy barrier. Thus, the rate of reaction increases.

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अध्याय 3: Chemical Kinetics - Exercises [पृष्ठ ८५]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 3 Chemical Kinetics
Exercises | Q 3.5 | पृष्ठ ८५

संबंधित प्रश्न

Define “zero order reaction”.


For a reaction: 

Rate = k

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.


For the first order thermal decomposition reaction, the following data were obtained:

Time / sec               Totalpressure / atm

0                              0.30

300                          0.50

Calculate the rate constant

(Given: log 2 = 0.301, log3 = 0.4771, log 4 = 0.6021)


For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

How is the rate of reaction affected if the concentration of B is doubled?


The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :

SO2Cl2 (g) → SO2 (g) + Cl2 (g)

Experiment Time/s–1 Total pressure/atm
1 0 0.4
2 100 0.7

Calculate the rate constant.

(Given : log 4 = 0.6021, log 2 = 0.3010)


From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.

\[\ce{C2H5Cl_{(g)} -> C2H4_{(g)} + HCl_{(g)}}\] Rate = k [C2H5Cl]


A reaction is first order in A and second order in B. How is the rate affected when the concentrations of both A and B are doubled?


Which of the following statement is true for order of a reaction?


Which of the following statements is not correct about order of a reaction.


Rate law for the reaction \[\ce{A + 2B -> C}\] is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be ______.


The value of rate constant of a pseudo first order reaction ______.


Why does the rate of any reaction generally decreases during the course of the reaction?


Assertion: Order of the reaction can be zero or fractional.

Reason: We cannot determine order from balanced chemical equation.


The role of a catalyst is to change


The number of molecules of the reactants taking part in a single step of the reaction is indicative of ______.


The conversion of molecules A to B follow second order kinetics. If concentration of A is increased to three times, how will it affect the rate of formation of B?


On heating compound (A) gives a gas (B) which is constituent of air. The gas when treated with H2 in the presence of catalyst gives another gas (C) which is basic in nature, (A) should not be ______.


Assertion (A): Order of reaction is applicable to elementary as well as complex reactions.

Reason (R): For a complex reaction, molecularity has no meaning.


A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?


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