हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?

Advertisements
Advertisements

प्रश्न

A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is doubled?

संख्यात्मक
Advertisements

उत्तर

\[\ce{Reactant -> Product}\]

Rate of reaction (R) = k [A]2

If the concentration of the reactant is doubled, i.e., [A] = 2A, then the rate of the reaction would be,

R = k[2A]2

= k 4 A2

= 4 kA2

Change in rate of reaction = `"rate of reaction when concentration is doubled"/"rate of reaction originally"`

= `(4 kA^2)/(kA^2)`

= 4 : 1

When the concentration is doubled, the reaction rate increases by a factor of 4.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 3: Chemical Kinetics - Exercises [पृष्ठ ८५]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 3 Chemical Kinetics
Exercises | Q 3.6 (i) | पृष्ठ ८५
नूतन Chemistry [English] Class 12 ISC
अध्याय 3 Chemical Kinetics
'NCERT TEXT-BOOK' Exercises | Q 4.6 i. | पृष्ठ २७८

संबंधित प्रश्न

Define “zero order reaction”.


For a reaction : 

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.


For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :

t/s 0 30 60
[CH3COOCH3] / mol L–1 0.60 0.30 0.15

(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.

(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.

(Given log 2 = 0.3010, log 4 = 0.6021)


Write resonating structures of ozone.


Define the following term:

Pseudo first-order reaction


What is the order of a reaction which has a rate expression; Rate = `"k"["A"]^(3/2)["B"]^1`?


Which of the following statements is not correct about order of a reaction.


Rate law for the reaction \[\ce{A + 2B -> C}\] is found to be Rate = k [A][B]. Concentration of reactant ‘B’ is doubled, keeping the concentration of ‘A’ constant, the value of rate constant will be ______.


Compounds ‘A’ and ‘B’ react according to the following chemical equation.
\[\ce{A(g) + 2B(g) -> 2C(g)}\]
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants constant and rates were measured as a function of initial concentration. Following results were obtained. Choose the correct option for the rate equations for this reaction.

Experiment Initial
concentration
of [A]/mol L–¹
Initial
concentration
of [B]/mol L–¹
Initial rate of
formation of
[C]/mol L–¹ s–¹
1. 0.30 0.30 0.10
2. 0.30 0.60 0.40
3. 0.60 0.30 0.20

For a complex reaction:

(i) order of overall reaction is same as molecularity of the slowest step.

(ii) order of overall reaction is less than the molecularity of the slowest step.

(iii) order of overall reaction is greater than molecularity of the slowest step.

(iv) molecularity of the slowest step is never zero or non interger.


Why does the rate of any reaction generally decreases during the course of the reaction?


Use Molecular Orbital theory to determine the bond order in each of species, [He2j+ and [He2]2+?


In the presence of a catalyst, the heat evolved or absorbed during the reaction.


The rate constant for the reaction \[\ce{2H2O5 -> 4NO2 + O2}\] is 30 × 10–5 sec–1. if the rate is 204 × 10–5 mol L–1 S–1, then the concentration of N2O5 (in mol–1) is-


At concentration of 0.1 and 0.2 mol L–1 the rates of deem position of a compound were found to be 0.18 and 0.72 mol L–1 m–1. What is the order of the reaction?


On heating compound (A) gives a gas (B) which is constituent of air. The gas when treated with H2 in the presence of catalyst gives another gas (C) which is basic in nature, (A) should not be ______.


A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is reduced to half?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×