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प्रश्न
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
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उत्तर
Both geometrical (cis, trans) and optical isomers for cis are possible.
(a) Geometrical isomers (cis-trans):
(b) Optical isomers of cis (d and l):
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संबंधित प्रश्न
When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.
Write the IUPAC name of [Co(en)2Cl2]+ ion.
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Name the type of isomerism shown by the following pair of compounds:
[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br
The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
\[\ce{[Pt(NH3 )(H2O)Cl2]}\]
