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प्रश्न
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
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उत्तर
Both geometrical (cis, trans) and optical isomers for cis are possible.
(a) Geometrical isomers (cis-trans):
(b) Optical isomers of cis (d and l):
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संबंधित प्रश्न
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(en)3]Cl3
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Write the IUPAC name of [Co(en)2Cl2]+ ion.
Name the type of isomerism shown by the following pair of compounds:
[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br
The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
