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Balance the following ionic equations. MnOX4−+HX++BrX−⟶MnX2++BrX2+HX2O

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प्रश्न

Balance the following ionic equations.

\[\ce{MnO^{-}4 + H^{+} + Br^{-} -> Mn^{2+} + Br2 + H2O}\]

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उत्तर


Dividing the equation into two half-reactions:

Oxidation half-reaction: \[\ce{Br^{-} -> Br2}\]

Reduction half-reaction: \[\ce{MnO^{-}4 -> Mn^{2+}}\]

Balancing oxidation and reduction half-reactions separately as:

Oxidation half-reaction:

\[\ce{Br^{-} -> Br2}\]

\[\ce{2Br^{-} -> Br2}\]

\[\ce{2Br^{-} -> Br2 + 2e-}\]  .....(i)

Reduction half-reaction:

\[\ce{MnO^{-}4 -> Mn^{2+}}\]

\[\ce{MnO^{-}4 + 5e^{-} -> Mn^{2+}}\]

\[\ce{MnO^{-}4 + 8H^{+} + 5e^{-} -> Mn^{2+}}\]

\[\ce{MnO^{-}4 + 8H^{+} + 5e^{-} -> Mn^{2+} + 4H2O}\] .....(ii)

To balance the electrons, multiply equation (i) by 5 and equation (ii) by 2 and add

\[\ce{2MnO^{-}4 + 10Br^{-} + 16H^{+} -> 2Mn^{2+} + 5Br2 + 8H2O}\]

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अध्याय 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ १०८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
अध्याय 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 26.(iv) | पृष्ठ १०८

संबंधित प्रश्न

Consider the reaction:

\[\ce{O3(g) + H2O2(l) → H2O(l) + 2O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{O3(g) + H2O2 (l) → H2O(l) + O2(g) + O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


Balance the following redox reactions by ion-electron method:

  1. \[\ce{MnO-_4 (aq) + I– (aq) → MnO2 (s) + I2(s) (in basic medium)}\]
  2. \[\ce{MnO-_4 (aq) + SO2 (g) → Mn^{2+} (aq) + HSO-_4  (aq) (in acidic solution)}\]
  3. \[\ce{H2O2 (aq) + Fe^{2+} (aq) → Fe^{3+} (aq) + H2O (l) (in acidic solution)}\]
  4. \[\ce{Cr_2O^{2-}_7 + SO2(g) → Cr^{3+} (aq) + SO^{2-}_4 (aq) (in acidic solution)}\]

Balance the following equation in the basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.

\[\ce{N2H4(l) + ClO^-_3 (aq) → NO(g) + Cl–(g)}\]


Balance the following equation in basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.

\[\ce{Cl_2O_{7(g)} + H_2O_{2(aq)} -> ClO-_{2(aq)} + O_{2(g)} + H+_{(aq)}}\]


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\[\ce{2Cu2O_{(S)} + Cu2S_{(S)}->6Cu_{(S)} + SO2_{(g)}}\]


Balance the following reaction by oxidation number method.

\[\ce{MnO^-_{4(aq)} + Br^-_{ (aq)}->MnO2_{ (s)} + BrO^-_{3(aq)}(basic)}\]


Balance the following reaction by oxidation number method.

\[\ce{H2SO4_{(aq)} + C_{(s)} -> CO2_{(g)}  + SO2_{(g)} + H2O_{(l)}(acidic)}\]


Balance the following redox equation by half-reaction method.

\[\ce{Bi(OH)_{3(s)} + SnO^2-_{2(aq)}->SnO^2-_{3(aq)} + Bi^_{(s)}(basic)}\]


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\[\ce{{x}H2O2_{(aq)} + ClO^-_{4(aq)} -> 2O2_{(g)} + ClO^-_{2(aq)} + {y}H2O_{(l)}}\]


Consider the reaction:

\[\ce{6 CO2(g) + 6H2O(l) → C6 H12O6(aq) + 6O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{6CO2(g) + 12H2O(l) → C6 H12O6(aq) + 6H2O(l) + 6O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


Balance the following equations by the oxidation number method.

\[\ce{Fe^{2+} + H^{+} + Cr2O^{2-}7 -> Cr^{3+} + Fe^{3+} + H2O}\]


Balance the following equations by the oxidation number method.

\[\ce{I2 + S2O^{2-}3 -> I- + S4O^{2-}6}\]


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\[\ce{Fe2O3 (s) + 3CO (g) ->[Δ] 2Fe (s) + 3CO2 (g)}\]


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\[\ce{PCl3 (l) + 3H2O (l) -> 3HCl (aq) + H3PO3 (aq)}\]


Identify the redox reactions out of the following reactions and identify the oxidising and reducing agents in them.

\[\ce{4NH3 (g) + 3O2 (g) -> 2N2 (g) + 6H2O (g)}\]


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\[\ce{xMnO^-_4 + yC2O^{2-}_4 + zH^+ -> xMn^{2+} + 2{y}CO2 + z/2H2O}\]

The values of x, y, and z in the reaction are, respectively:


\[\ce{H2O2 -> 2H^+ + O2 + 2e^-}\]; E0 = −0.68 V.

This equation represents which of the following behaviour of H2O2?


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