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Balance the following ionic equations. MnOX4−+HX++BrX−⟶MnX2++BrX2+HX2O

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प्रश्न

Balance the following ionic equations.

\[\ce{MnO^{-}4 + H^{+} + Br^{-} -> Mn^{2+} + Br2 + H2O}\]

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उत्तर


Dividing the equation into two half-reactions:

Oxidation half-reaction: \[\ce{Br^{-} -> Br2}\]

Reduction half-reaction: \[\ce{MnO^{-}4 -> Mn^{2+}}\]

Balancing oxidation and reduction half-reactions separately as:

Oxidation half-reaction:

\[\ce{Br^{-} -> Br2}\]

\[\ce{2Br^{-} -> Br2}\]

\[\ce{2Br^{-} -> Br2 + 2e-}\]  .....(i)

Reduction half-reaction:

\[\ce{MnO^{-}4 -> Mn^{2+}}\]

\[\ce{MnO^{-}4 + 5e^{-} -> Mn^{2+}}\]

\[\ce{MnO^{-}4 + 8H^{+} + 5e^{-} -> Mn^{2+}}\]

\[\ce{MnO^{-}4 + 8H^{+} + 5e^{-} -> Mn^{2+} + 4H2O}\] .....(ii)

To balance the electrons, multiply equation (i) by 5 and equation (ii) by 2 and add

\[\ce{2MnO^{-}4 + 10Br^{-} + 16H^{+} -> 2Mn^{2+} + 5Br2 + 8H2O}\]

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पाठ 8: Redox Reactions - Multiple Choice Questions (Type - I) [पृष्ठ १०८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 26.(iv) | पृष्ठ १०८

संबंधित प्रश्‍न

Whenever a reaction between an oxidising agent and a reducing agent is carried out, a compound of lower oxidation state is formed if the reducing agent is in excess and a compound of higher oxidation state is formed if the oxidising agent is in excess. Justify this statement giving three illustrations.


How do you count for the following observations?

Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant. Why? Write a balanced redox equation for the reaction.


Balance the following equation in basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.

\[\ce{P4(s) + OH–(aq) —> PH3(g) + HPO^–_2(aq)}\]


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\[\ce{N2H4(l) + ClO^-_3 (aq) → NO(g) + Cl–(g)}\]


Balance the following equation in basic medium by ion-electron method and oxidation number methods and identify the oxidising agent and the reducing agent.

\[\ce{Cl_2O_{7(g)} + H_2O_{2(aq)} -> ClO-_{2(aq)} + O_{2(g)} + H+_{(aq)}}\]


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Balance the following reaction by oxidation number method.

\[\ce{Cr2O^2-_{7(aq)} + SO^2-_{3(aq)}->Cr^3+_{ (aq)} + SO^2-_{4(aq)}(acidic)}\]


Balance the following reaction by oxidation number method.

\[\ce{MnO^-_{4(aq)} + Br^-_{ (aq)}->MnO2_{ (s)} + BrO^-_{3(aq)}(basic)}\]


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\[\ce{Bi(OH)_{3(s)} + SnO^2-_{2(aq)}->SnO^2-_{3(aq)} + Bi^_{(s)}(basic)}\]


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\[\ce{CH4_{(g)} + 2O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)}}\]


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\[\ce{6 CO2(g) + 6H2O(l) → C6 H12O6(aq) + 6O2(g)}\]

Why it is more appropriate to write these reaction as:

\[\ce{6CO2(g) + 12H2O(l) → C6 H12O6(aq) + 6H2O(l) + 6O2(g)}\]

Also, suggest a technique to investigate the path of the redox reactions.


Write balanced chemical equation for the following reactions:

Permanganate ion \[\ce{(MnO^{-}4)}\] reacts with sulphur dioxide gas in acidic medium to produce \[\ce{Mn^{2+}}\] and hydrogen sulphate ion.


Balance the following equations by the oxidation number method.

\[\ce{Fe^{2+} + H^{+} + Cr2O^{2-}7 -> Cr^{3+} + Fe^{3+} + H2O}\]


Balance the following equations by the oxidation number method.

\[\ce{I2 + S2O^{2-}3 -> I- + S4O^{2-}6}\]


Balance the following equations by the oxidation number method.

\[\ce{MnO2 + C2O^{2-}4 -> Mn^{2+} + CO2}\]


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\[\ce{Cr2O^{2-}7 + H^{+} + I- -> Cr^{3+} + I2 + H2O}\]


Balance the following ionic equations.

\[\ce{Cr2O^{2-}7 + Fe^{2+} + H+ -> Cr^{3+} + Fe^{3+} + H2O}\]


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