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Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution. - Chemistry

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प्रश्न

Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.

विकल्प

  • Assertion and reason both are correct and reason is correct explanation of assertion.

  • Assertion and reason both are wrong statements.

  • Assertion is correct but reason is wrong statement.

  • Assertion is wrong but reason is correct statement.

  • Assertion and reason both are correct statements but reason is not correct explanation of assertion.

MCQ
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उत्तर

Assertion and reason both are correct and reason is correct explanation of assertion.

Explanation:

Nitro group being electron withdrawing group, decreases the electron density of ring hence increase the reactivity of haloarenes towards nucleophilic substitution.

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अध्याय 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४८]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 10 Haloalkanes and Haloarenes
Exercises | Q V. 89. | पृष्ठ १४८

संबंधित प्रश्न

Write the final product(s) in each of the following reactions:


How the following conversion can be carried out?

Chlorobenzene to p-nitrophenol


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Write the product formed on reaction of D-glucose with Br2 water.


Write chemical equation in support of your answer. 
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Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Haloarenes are less reactive than haloalkanes and haloalkenes. Explain.


Allyl chloride is hydrolysed more readily than n-propyl chloride. Why?


\[\ce{C6H12O6 ->[(Zymase)] A ->[NaOH][\Delta] B + CHI3}\]

The number of carbon atoms present in the product B is:


Assertion: Chlorobenzene is resistant to nucleophilic substitution reaction at room temperature.

Reason (R): C–Cl bond gets weaker due, to resonance.


Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.


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