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Haloarenes are less reactive than haloalkanes and haloalkenes. Explain. - Chemistry

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प्रश्न

Haloarenes are less reactive than haloalkanes and haloalkenes. Explain.

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उत्तर

In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.

C-Cl bond acquires a partial double bond character due to resonance. As a result, the bond cleavage in haloarene is difficult than haloalkane and therefore, they are less reactive towards nucleophilic substitution reaction.

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अध्याय 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४३]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 10 Haloalkanes and Haloarenes
Exercises | Q III. 48. | पृष्ठ १४३

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(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
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\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
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\end{array}\]

 

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\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


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