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Allyl chloride is hydrolysed more readily than n-propyl chloride. Why? - Chemistry

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प्रश्न

Allyl chloride is hydrolysed more readily than n-propyl chloride. Why?

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उत्तर

Allyl chloride shows high reactivity because the carbocation formed by hydrolysis is stabilised by resonance while no such stabilisation of carbocation exists in the case of n-propyl chloride.

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अध्याय 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४४]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 10 Haloalkanes and Haloarenes
Exercises | Q III. 65. | पृष्ठ १४४

संबंधित प्रश्न

What happens when \[\ce{CH3 - Br}\] is treated with KCN?


Chlorobenzene is extremely less reactive towards a nucleophilic substitution reaction. Give two reasons for the same.


Write the final product(s) in each of the following reactions:


The presence of nitro group (−NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.


How the following conversion can be carried out?

Chlorobenzene to p-nitrophenol


Give reasons:

The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.


Write the product formed on reaction of D-glucose with Br2 water.


Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 


Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.


Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

\[\ce{C6H12O6 ->[(Zymase)] A ->[NaOH][\Delta] B + CHI3}\]

The number of carbon atoms present in the product B is:


Assertion: Chlorobenzene is resistant to nucleophilic substitution reaction at room temperature.

Reason (R): C–Cl bond gets weaker due, to resonance.


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