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प्रश्न
Allyl chloride is hydrolysed more readily than n-propyl chloride. Why?
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उत्तर
Allyl chloride shows high reactivity because the carbocation formed by hydrolysis is stabilised by resonance while no such stabilisation of carbocation exists in the case of n-propyl chloride.
संबंधित प्रश्न
What happens when \[\ce{CH3 - Br}\] is treated with KCN?
Write the final product(s) in each of the following reactions:
How the following conversion can be carried out?
Chlorobenzene to p-nitrophenol
Give reasons:
The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.
Write the product formed on reaction of D-glucose with Br2 water.
What is Grignard reagent?
Out of (CH3)3 C-Br and (CH3)3 C-I, which one is more reactive towards SN1 and why?
Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.
Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.
Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?
(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]
(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]
(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]
Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.
| (a) |  |
| (b) |  |
| (c) |  |
Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.
| (a) |  |
| (b) |  |
| (c) |  |
Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.
| (a) |  |
| (b) |  |
| (c) |  |
Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.
| (a) |  |
| (b) |  |
| (c) |  |
Haloarenes are less reactive than haloalkanes and haloalkenes. Explain.
Assertion: Chlorobenzene is resistant to nucleophilic substitution reaction at room temperature.
Reason (R): C–Cl bond gets weaker due, to resonance.
