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Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.

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प्रश्न

Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.

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उत्तर

Haloarenes are not reactive towards nucleophilic substitution reactions because of two reasons:

  1. The difference in the hybridisation of carbon atoms is the bond.
  2. Instability of phenyl cation.
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2022-2023 (March) Delhi Set 3

वीडियो ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्न

Write the final product(s) in each of the following reactions:


Write the product formed on reaction of D-glucose with Br2 water.


What is Grignard reagent?


Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 


Out of (CH3)3 C-Br and (CH3)3 C-I, which one is more reactive towards SN1 and why? 


Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?

(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

\[\ce{C6H12O6 ->[(Zymase)] A ->[NaOH][\Delta] B + CHI3}\]

The number of carbon atoms present in the product B is:


Assertion: Chlorobenzene is resistant to nucleophilic substitution reaction at room temperature.

Reason (R): C–Cl bond gets weaker due, to resonance.


Identify the final product [D] obtained in the following sequence of reactions.

\[\ce{CH3CHO \underset{ii) H2O+}{\overset{i) LiAlH4}{->}} [A] \underset{\triangle}{\overset{H2SO4}{->}} [B]}\]


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