Advertisements
Advertisements
प्रश्न
\[\ce{\Lambda^0_m(NH4OH)}\] is equal to ______.
विकल्प
\[\ce{\Lambda^0_m(NH4OH) + \Lambda^0_m(NH4Cl) - \Lambda^0(HCl)}\]
\[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0(NaCl)}\]
\[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaCl) - \Lambda^0(NaOH)}\]
\[\ce{\Lambda^0_m(NaOH) + \Lambda^0_m(NaCl) - \Lambda^0(NH4Cl)}\]
Advertisements
उत्तर
\[\ce{\Lambda^0_m(NH4OH)}\] is equal to \[\ce{\mathbf{\underline{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0_m(NaCl)}}}\]
Explanation:
(i) \[\ce{NH4Cl <=> NH^{+}4 + Cl-}\]
(ii) \[\ce{NaCl <=> Na+ + Cl-}\]
(iii) \[\ce{NaOH <=> Na+ + OH-}\]
(iv) \[\ce{NH4OH <=> NH^{+}4 + OH-}\]
To get equation (iv),
\[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0(NaCl) = \Lambda^0_m(NH_4OH)}\]
APPEARS IN
संबंधित प्रश्न
State Kohlrausch’s law of independent migration of ions.
Define limiting molar conductivity.
Why does the conductivity of a solution decrease with dilution?
Define the following terms: Molar conductivity (⋀m)
The conductivity of sodium chloride at 298 K has been determined at different concentrations and the results are given below:
| Concentration/M | 0.001 | 0.010 | 0.020 | 0.050 | 0.100 |
| 102 × κ/S m−1 | 1.237 | 11.85 | 23.15 | 55.53 | 106.74 |
Calculate ∧m for all concentrations and draw a plot between ∧m and c1/2. Find the value of `Lambda_m^0`.
10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant gram molarity of solution is _______.
(A) 0.25 M
(B) 0.5 M
(C) 1.0 M
(D) 0.1 M
Define the following terms :
Limiting molar conductivity
Conductivity always decreases with decrease in concentration both, for weak and strong electrolytes because of the fact that ____________.
Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer.
Write the cell reaction of a lead storage battery when it is discharged. How does the density of the electrolyte change when the battery is discharged?
Match the items of Column I and Column II on the basis of data given below:
`E_("F"_2//"F"^-)^Θ` = 2.87 V, `"E"_(("Li"^(+))//("Li"^-))^Θ` = − 3.5V, `"E"_(("Au"^(3+))//("Au"))^Θ` = 1.4 V, `"E"_(("Br"_(2))//("Br"^-))^Θ` = 1.09 V
| Column I | Column II |
| (i) F2 | (a) metal is the strongest reducing agent |
| (ii) Li | (b) metal ion which is the weakest oxidising agent |
| (iii) Au3+ | (c) non metal which is the best oxidising agent |
| (iv) Br– | (d) unreactive metal |
| (v) Au | (e) anion that can be oxidised by Au3+ |
| (vi) Li+ | (f) anion which is the weakest reducing agent |
| (vii) F– | (g) metal ion which is an oxidising agent |
Assertion: Copper sulphate can be stored in zinc vessel.
Reason: Zinc is less reactive than copper.
Consider figure and answer the question to given below.
How will the concentration of Zn2+ ions and Ag+ ions be affected after the cell becomes ‘dead’?
An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to :-
Which of the following increases with the increase in the concentration of the solution?
The molar conductance of NaCl, HCl and CH3COONa at infinite dilution are 126.45, 426.16 and 91.0 S cm2 mol−1 respectively. The molar conductance of CH3COOH at infinite dilution is ______.
Choose the right option for your answer.
The molar conductance of NaCl, HCl, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm2 mol−1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.
The molar conductivity of CH3COOH at infinite dilution is 390 Scm2/mol. Using the graph and given information, the molar conductivity of CH3COOK will be:

The solubility of Co2[Fe(CN)6] in water at 25°C from the following data:
Conductivity of saturated solution of Co2[Fe(CN)6] = 2.06 × 10−6 ohm−1 cm−1 and that of water = 4.1 × 10−7 ohm−1 cm−1. The ionic molar conductivities of Co2+ and [Fe(CN)6]4− are 86 and 444 ohm−1 cm2 mol−1 respectively, is ______ × 10−6 mol/L.
The unit of molar conductivity is ______.
