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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Λ⁢0𝑚⁢(NH⁢4⁢OH) is equal to ______.

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प्रश्न

\[\ce{\Lambda^0_m(NH4OH)}\] is equal to ______.

विकल्प

  • \[\ce{\Lambda^0_m(NH4OH) + \Lambda^0_m(NH4Cl) - \Lambda^0(HCl)}\]

  • \[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0(NaCl)}\]

  • \[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaCl) - \Lambda^0(NaOH)}\]

  • \[\ce{\Lambda^0_m(NaOH) + \Lambda^0_m(NaCl) - \Lambda^0(NH4Cl)}\]

MCQ
रिक्त स्थान भरें
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उत्तर

\[\ce{\Lambda^0_m(NH4OH)}\] is equal to \[\ce{\mathbf{\underline{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0_m(NaCl)}}}\]

Explanation:

(i) \[\ce{NH4Cl <=> NH^{+}4 + Cl-}\]  

(ii) \[\ce{NaCl <=> Na+ + Cl-}\]  

(iii) \[\ce{NaOH <=> Na+ + OH-}\]   

(iv) \[\ce{NH4OH <=> NH^{+}4 + OH-}\] 

To get equation (iv),

\[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0(NaCl) = \Lambda^0_m(NH_4OH)}\]

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अध्याय 3: Electrochemistry - Exercises [पृष्ठ ३६]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 3 Electrochemistry
Exercises | Q I. 16. | पृष्ठ ३६

संबंधित प्रश्न

Define “Molar conductivity”.


State Kohlrausch’s law of independent migration of ions.


 

The molar conductivity of cation and anion of salt BA are 180 and 220 mhos respectively. The molar conductivity of salt BA at infinite dilution is_____________ .

(a) 90 mhos.cm2                                                                             

(b) 110 mhos.cm2.mol-1

(c) 200 mhos.cm2.mol-1                                                                 

(d) 400 mhos.cm2.mol-1


State Kohlrausch Law.


The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.


The conductivity of 0.20 mol L−1 solution of KCl is 2.48 × 10−2 S cm−1. Calculate its molar conductivity and degree of dissociation (α). Given λ0 (K+) = 73.5 S cm2 mol−1 and λ0 (C1) = 76.5 S cm2 mol−1.


Conductivity of 0.00241 M acetic acid is 7.896 × 10−5 S cm−1. Calculate its molar conductivity and if `Lambda_m^0` for acetic acid is 390.5 S cm2 mol−1, what is its dissociation constant?


The conductivity of 0.02 M AgNO3 at 25°C is 2.428 × 103 Ω1 cm1. What is its molar conductivity?


Conductivity always decreases with decrease in concentration both, for weak and strong electrolytes because of the fact that ____________.


\[\ce{Λ^0_m H2O}\] is equal to:

(i) \[\ce{Λ^0_m_{(HCl)} + \ce{Λ^0_m_{(NaOH)} - \ce{Λ^0_m_{(NaCl)}}}}\]

(ii) \[\ce{Λ^0_m_{(HNO_3)} + \ce{Λ^0_m_{(NaNO_3)} - \ce{Λ^0_m_{(NaOH)}}}}\]

(iii) \[\ce{Λ^0_{(HNO_3)} + \ce{Λ^0_m_{(NaOH)} - \ce{Λ^0_m_{(NaNO_3)}}}}\]

(iv) \[\ce{Λ^0_m_{(NH_4OH)} + \ce{Λ^0_m_{(HCl)} - \ce{Λ^0_m_{(NH_4Cl)}}}}\]


Molar conductivity of ionic solution depends on:

(i) temperature.

(ii) distance between electrodes.

(iii) concentration of electrolytes in solution.

(iv) surface area of electrodes.


Write the cell reaction of a lead storage battery when it is discharged. How does the density of the electrolyte change when the battery is discharged?


Match the items of Column I and Column II on the basis of data given below:

`E_("F"_2//"F"^-)^Θ` = 2.87 V, `"E"_(("Li"^(+))//("Li"^-))^Θ` = − 3.5V, `"E"_(("Au"^(3+))//("Au"))^Θ` = 1.4 V, `"E"_(("Br"_(2))//("Br"^-))^Θ` = 1.09 V

Column I Column II
(i) F2 (a) metal is the strongest reducing agent
(ii) Li (b) metal ion which is the weakest oxidising agent
(iii) Au3+ (c) non metal which is the best oxidising agent
(iv) Br (d) unreactive metal
(v) Au (e) anion that can be oxidised by Au3+
(vi) Li+ (f) anion which is the weakest reducing agent
(vii) F (g) metal ion which is an oxidising agent

Assertion: Λm for weak electrolytes shows a sharp increase when the electrolytic solution is diluted.

Reason: For weak electrolytes degree of dissociation increases with dilution of solution.


Assertion: `"E"_("Ag"^+ //"Ag")` increases with increase in concentration of Ag+ ions.

Reason: `"E"_("Ag"^+ //"Ag")` has a positive value.


The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol−1. What is the dissociation constant of acetic acid? Choose the correct option.

\[\begin{array}{cc}
\end{array}\]\[\begin{bmatrix}
\ce{\Lambda^{\circ}_{H^+} = 350 S cm^2 mol^{-1}}\\
\ce{\Lambda^{\circ}_{CH_3COO^-} = 50 S cm^2 mol^{-1}}
\end{bmatrix}\]


Molar conductivity of substance “A” is 5.9 × 103 S/m and “B” is 1 × 10–16 S/m. Which of the two is most likely to be copper metal and why?


The solution of two electrolytes A and B are diluted. ^m of B increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Give a reason.


Suggest a way to determine the \[\ce{\Lambda^{\circ}_m}\] value of water.


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