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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Λ⁢0𝑚⁢(NH⁢4⁢OH) is equal to ______.

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प्रश्न

\[\ce{\Lambda^0_m(NH4OH)}\] is equal to ______.

विकल्प

  • \[\ce{\Lambda^0_m(NH4OH) + \Lambda^0_m(NH4Cl) - \Lambda^0(HCl)}\]

  • \[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0(NaCl)}\]

  • \[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaCl) - \Lambda^0(NaOH)}\]

  • \[\ce{\Lambda^0_m(NaOH) + \Lambda^0_m(NaCl) - \Lambda^0(NH4Cl)}\]

MCQ
रिक्त स्थान भरें
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उत्तर

\[\ce{\Lambda^0_m(NH4OH)}\] is equal to \[\ce{\mathbf{\underline{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0_m(NaCl)}}}\]

Explanation:

(i) \[\ce{NH4Cl <=> NH^{+}4 + Cl-}\]  

(ii) \[\ce{NaCl <=> Na+ + Cl-}\]  

(iii) \[\ce{NaOH <=> Na+ + OH-}\]   

(iv) \[\ce{NH4OH <=> NH^{+}4 + OH-}\] 

To get equation (iv),

\[\ce{\Lambda^0_m(NH4Cl) + \Lambda^0_m(NaOH) - \Lambda^0(NaCl) = \Lambda^0_m(NH_4OH)}\]

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अध्याय 3: Electrochemistry - Exercises [पृष्ठ ३६]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 3 Electrochemistry
Exercises | Q I. 16. | पृष्ठ ३६

संबंधित प्रश्न

State Kohlrausch’s law of independent migration of ions.


The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.


Why conductivity of an electrolyte solution decreases with the decrease in concentration ?


The molar conductivity of 0.025 mol L−1 methanoic acid is 46.1 S cm2 mol1. Calculate its degree of dissociation and dissociation constant. Given \[\ce{λ^0_{(H^+)}}\] = 349.6 S cm2 mol1 and \[\ce{λ^0_{(HCOO^-)}}\] = 54.6 S cm2 mol1.


The conductivity of sodium chloride at 298 K has been determined at different concentrations and the results are given below:

Concentration/M 0.001 0.010 0.020 0.050 0.100
102 × κ/S m−1 1.237 11.85 23.15 55.53 106.74

Calculate ∧m for all concentrations and draw a plot between ∧m and c1/2. Find the value of `Lambda_m^0`.


Calculate the degree of dissociation (α) of acetic acid if its molar conductivity (Λm) is 39.05 S cm2 mol−1.

(Given \[\ce{\lambda^{\circ}_{(H^+)}}\] = 349.6 S cm2 mol−1 and \[\ce{\lambda^{\circ}_{(CH_3COO^-)}}\] = 40.95 S cm2 mol−1)


Molar conductivity denoted by the symbol Λm is related to the conductivity of the solution by the equation (k is the conductivity and c is the concentration).


Which of the statements about solutions of electrolytes is not correct?


Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer.


When acidulated water (dil.H2SO4 solution) is electrolysed, will the pH of the solution be affected? Justify your answer.


Match the items of Column I and Column II on the basis of data given below:

`E_("F"_2//"F"^-)^Θ` = 2.87 V, `"E"_(("Li"^(+))//("Li"^-))^Θ` = − 3.5V, `"E"_(("Au"^(3+))//("Au"))^Θ` = 1.4 V, `"E"_(("Br"_(2))//("Br"^-))^Θ` = 1.09 V

Column I Column II
(i) F2 (a) metal is the strongest reducing agent
(ii) Li (b) metal ion which is the weakest oxidising agent
(iii) Au3+ (c) non metal which is the best oxidising agent
(iv) Br (d) unreactive metal
(v) Au (e) anion that can be oxidised by Au3+
(vi) Li+ (f) anion which is the weakest reducing agent
(vii) F (g) metal ion which is an oxidising agent

Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer. Graphically show the behavior of ‘A’ and ‘B’.


An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to :-


Which of the following increases with the increase in the concentration of the solution?


The molar conductance of NaCl, HCl and CH3COONa at infinite dilution are 126.45, 426.16 and 91.0 S cm2 mol−1 respectively. The molar conductance of CH3COOH at infinite dilution is ______.

Choose the right option for your answer.


Which of the following solutions of KCl will have the highest value of molar conductivity?


Assertion (A) : Conductivity decreases with decrease in concentration of electrolyte.

Reason (R) : Number of ions per unit volume that carry the current in a solution decreases on dilution.


Which of the following solutions will have the highest conductivity at 298 K? 


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