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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Match the items of Column I and Column II on the basis of data given below: EF2F-Θ = 2.87 V, ELi+Li-Θ = − 3.5V, EAu3+AuΘ = 1.4 V, EBr2Br-Θ = 1.09 V Column I Column II (i) F2 (a) metal is the stronges

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प्रश्न

Match the items of Column I and Column II on the basis of data given below:

`E_("F"_2//"F"^-)^Θ` = 2.87 V, `"E"_(("Li"^(+))//("Li"^-))^Θ` = − 3.5V, `"E"_(("Au"^(3+))//("Au"))^Θ` = 1.4 V, `"E"_(("Br"_(2))//("Br"^-))^Θ` = 1.09 V

Column I Column II
(i) F2 (a) metal is the strongest reducing agent
(ii) Li (b) metal ion which is the weakest oxidising agent
(iii) Au3+ (c) non metal which is the best oxidising agent
(iv) Br (d) unreactive metal
(v) Au (e) anion that can be oxidised by Au3+
(vi) Li+ (f) anion which is the weakest reducing agent
(vii) F (g) metal ion which is an oxidising agent
जोड़ियाँ मिलाइएँ
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उत्तर

Column I Column II
(i) F2 (c) non metal which is the best oxidising agent
(ii) Li (a) metal is the strongest reducing agent
(iii) Au3+ (g) metal ion which is an oxidising agent
(iv) Br (e) anion that can be oxidised by Au3+
(v) Au (d) unreactive metal
(vi) Li+ (b) metal ion which is the weakest oxidising agent
(vii) F (f) anion which is the weakest reducing agent
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अध्याय 3: Electrochemistry - Exercises [पृष्ठ ४१]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 3 Electrochemistry
Exercises | Q IV. 55. | पृष्ठ ४१

संबंधित प्रश्न

The conductivity of 0.20 M solution of KCl at 298 K is 0.025 S cm−1. Calculate its molar conductivity.


The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.


Why does the conductivity of a solution decrease with dilution?


The conductivity of sodium chloride at 298 K has been determined at different concentrations and the results are given below:

Concentration/M 0.001 0.010 0.020 0.050 0.100
102 × κ/S m−1 1.237 11.85 23.15 55.53 106.74

Calculate ∧m for all concentrations and draw a plot between ∧m and c1/2. Find the value of `Lambda_m^0`.


Write mathematical expression of molar conductivity of the given solution at infinite dilution.


Calculate the degree of dissociation (α) of acetic acid if its molar conductivity (Λm) is 39.05 S cm2 mol−1.

(Given \[\ce{\lambda^{\circ}_{(H^+)}}\] = 349.6 S cm2 mol−1 and \[\ce{\lambda^{\circ}_{(CH_3COO^-)}}\] = 40.95 S cm2 mol−1)


Define the following terms :

Limiting molar conductivity


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In the plot of molar conductivity (∧m) vs square root of concentration (c1/2) following curves are obtained for two electrolytes A and B : 

Answer the following:
(i) predict the nature of electrolytes A and B.
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Which of the statements about solutions of electrolytes is not correct?


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Reason: For weak electrolytes degree of dissociation increases with dilution of solution.


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Reason: Zinc is less reactive than copper.


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The molar conductance of NaCl, HCl and CH3COONa at infinite dilution are 126.45, 426.16 and 91.0 S cm2 mol−1 respectively. The molar conductance of CH3COOH at infinite dilution is ______.

Choose the right option for your answer.


The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol−1. What is the dissociation constant of acetic acid? Choose the correct option.

\[\begin{array}{cc}
\end{array}\]\[\begin{bmatrix}
\ce{\Lambda^{\circ}_{H^+} = 350 S cm^2 mol^{-1}}\\
\ce{\Lambda^{\circ}_{CH_3COO^-} = 50 S cm^2 mol^{-1}}
\end{bmatrix}\]


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Conductivity of saturated solution of Co2[Fe(CN)6] = 2.06 × 10−6 ohm−1 cm−1 and that of water = 4.1 × 10−7 ohm−1 cm−1. The ionic molar conductivities of Co2+ and [Fe(CN)6]4− are 86 and 444 ohm−1 cm2 mol−1 respectively, is ______ × 10−6 mol/L.


Conductivity of 2 × 10−3 M methanoic acid is 8 × 10−5 S cm−1. Calculate its molar conductivity and degree of dissociation if `∧_"m"^0` for methanoic acid, is 404 S cm2 mol−3.


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