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प्रश्न
Define limiting molar conductivity.
Define the following term:
Limiting molar conductivity (∧°m)
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उत्तर १
The limiting molar conductivity of an electrolyte is defined as its molar conductivity when the concentration of the electrolyte in the solution approaches zero.
उत्तर २
When the concentration of an electrolytic solution placed between electrodes of a conductivity cell placed at a unit distance having an area of cross-section sufficient to accommodate enough volume of solution containing one mole of electrolyte approaches zero, then the conductance of the solution is known as limiting molar conductivity.
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संबंधित प्रश्न
State Kohlrausch’s law of independent migration of ions.
The conductivity of 0.20 M solution of KCl at 298 K is 0.025 S cm−1. Calculate its molar conductivity.
State Kohlrausch Law.
Why does the conductivity of a solution decrease with dilution?
Write mathematical expression of molar conductivity of the given solution at infinite dilution.
Molar conductivity of ionic solution depends on:
(i) temperature.
(ii) distance between electrodes.
(iii) concentration of electrolytes in solution.
(iv) surface area of electrodes.
Why on dilution the m Λm of \[\ce{CH3COOH}\] increases very fast, while that of \[\ce{CH3COONa}\] increases gradually?
Assertion: `"E"_("Ag"^+ //"Ag")` increases with increase in concentration of Ag+ ions.
Reason: `"E"_("Ag"^+ //"Ag")` has a positive value.
The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol−1. What is the dissociation constant of acetic acid? Choose the correct option.
\[\begin{array}{cc}
\end{array}\]\[\begin{bmatrix}
\ce{\Lambda^{\circ}_{H^+} = 350 S cm^2 mol^{-1}}\\
\ce{\Lambda^{\circ}_{CH_3COO^-} = 50 S cm^2 mol^{-1}}
\end{bmatrix}\]
Which of the following solutions of KCl will have the highest value of molar conductivity?
