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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Copper sulphate can be stored in zinc vessel. Reason: Zinc is less reactive than copper.

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प्रश्न

Assertion: Copper sulphate can be stored in zinc vessel.

Reason: Zinc is less reactive than copper.

विकल्प

  • Both assertion and reason are true and the reason is the correct explanation of assertion.

  • Both assertion and reason are true and the reason is not the correct explanation of assertion.

  • Assertion is true but the reason is false.

  • Both assertion and reason are false.

  • Assertion is false but reason is true.

MCQ
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उत्तर

Both assertion and reason are false.

Explanation:

Zinc will get dissolved in CuS04 solution since zinc is more reactive than copper.

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अध्याय 3: Electrochemistry - Exercises [पृष्ठ ४२]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 3 Electrochemistry
Exercises | Q V. 65. | पृष्ठ ४२

संबंधित प्रश्न

The conductivity of 0.20 M solution of KCl at 298 K is 0.025 S cm−1. Calculate its molar conductivity.


The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.


The conductivity of 0.20 mol L−1 solution of KCl is 2.48 × 10−2 S cm−1. Calculate its molar conductivity and degree of dissociation (α). Given λ0 (K+) = 73.5 S cm2 mol−1 and λ0 (C1) = 76.5 S cm2 mol−1.


Conductivity of 0.00241 M acetic acid is 7.896 × 10−5 S cm−1. Calculate its molar conductivity and if `Lambda_m^0` for acetic acid is 390.5 S cm2 mol−1, what is its dissociation constant?


10.0 grams of caustic soda when dissolved in 250 cm3 of water, the resultant gram molarity of solution is _______.

(A) 0.25 M

(B) 0.5 M

(C) 1.0 M

(D) 0.1 M


The conductivity of 0.02 M AgNO3 at 25°C is 2.428 × 103 Ω1 cm1. What is its molar conductivity?


Write mathematical expression of molar conductivity of the given solution at infinite dilution.


 How can you determine limiting molar conductivity,   0 m for strong electrolyte and weak electrolyte?


In the plot of molar conductivity (∧m) vs square root of concentration (c1/2), following curves are obtained for two electrolytes A and B:

Answer the following:
(i) Predict the nature of electrolytes A and B.
(ii) What happens on extrapolation of ∧m to concentration approaching zero for electrolytes A and B?


Conductivity always decreases with decrease in concentration both, for weak and strong electrolytes because of the fact that ____________.


Kohlrausch law of independent migration of ions states ____________.


\[\ce{Λ^0_m H2O}\] is equal to:

(i) \[\ce{Λ^0_m_{(HCl)} + \ce{Λ^0_m_{(NaOH)} - \ce{Λ^0_m_{(NaCl)}}}}\]

(ii) \[\ce{Λ^0_m_{(HNO_3)} + \ce{Λ^0_m_{(NaNO_3)} - \ce{Λ^0_m_{(NaOH)}}}}\]

(iii) \[\ce{Λ^0_{(HNO_3)} + \ce{Λ^0_m_{(NaOH)} - \ce{Λ^0_m_{(NaNO_3)}}}}\]

(iv) \[\ce{Λ^0_m_{(NH_4OH)} + \ce{Λ^0_m_{(HCl)} - \ce{Λ^0_m_{(NH_4Cl)}}}}\]


Molar conductivity of ionic solution depends on:

(i) temperature.

(ii) distance between electrodes.

(iii) concentration of electrolytes in solution.

(iv) surface area of electrodes.


Match the items of Column I and Column II on the basis of data given below:

`E_("F"_2//"F"^-)^Θ` = 2.87 V, `"E"_(("Li"^(+))//("Li"^-))^Θ` = − 3.5V, `"E"_(("Au"^(3+))//("Au"))^Θ` = 1.4 V, `"E"_(("Br"_(2))//("Br"^-))^Θ` = 1.09 V

Column I Column II
(i) F2 (a) metal is the strongest reducing agent
(ii) Li (b) metal ion which is the weakest oxidising agent
(iii) Au3+ (c) non metal which is the best oxidising agent
(iv) Br (d) unreactive metal
(v) Au (e) anion that can be oxidised by Au3+
(vi) Li+ (f) anion which is the weakest reducing agent
(vii) F (g) metal ion which is an oxidising agent

Assertion: Λm for weak electrolytes shows a sharp increase when the electrolytic solution is diluted.

Reason: For weak electrolytes degree of dissociation increases with dilution of solution.


The molar conductance of NaCl, HCl, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm2 mol−1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.


Assertion (A) : Conductivity decreases with decrease in concentration of electrolyte.

Reason (R) : Number of ions per unit volume that carry the current in a solution decreases on dilution.


The resistance of a conductivity cell with a 0.1 M KCl solution is 200 ohm. When the same cell is filled with a 0.02 M NaCl solution, the resistance is 1100 ohm. If the conductivity of 0.1 M KCl solution is 0.0129 ohm-1 cm-1, calculate the cell constant and molar conductivity of 0.02 M NaCl solution.


The solution of two electrolytes A and B are diluted. ^m of B increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Give a reason.


Discuss the variation of conductivity and molar conductivity with concentration.


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