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प्रश्न
Which of the statements about solutions of electrolytes is not correct?
विकल्प
Conductivity of solution depends upon size of ions.
Conductivity depends upon viscosiy of solution.
Conductivity does not depend upon solvation of ions present in solution.
Conductivity of solution increases with temperature.
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उत्तर
Conductivity does not depend upon solvation of ions present in solution.
Explanation:
Conductivity depends upon salvation of ions present in the solution. The greater the salvation of ions, the lesser is the conductivity.
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संबंधित प्रश्न
Define “Molar conductivity”.
Resistance of conductivity cell filled with 0.1 M KCl solution is 100 ohms. If the resistance of the same cell when filled with 0.02 M KCl solution is 520 ohms, calculate the conductivity and molar conductivity of 0.02 M KCl solution. [Given: Conductivity of 0.1 M KCl solution is 1.29 S m-1 .]
State Kohlrausch’s law of independent migration of ions.
The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905× 10-5 S cm-1. Calculate its molar conductivity and degree of dissociation (α) Given λ°(H+)= 349.6 S cm2 mol-1 and λ°(CH3COO)= 40.9S cm2mol-1.
Why conductivity of an electrolyte solution decreases with the decrease in concentration ?
Why does the conductivity of a solution decrease with dilution?
The conductivity of sodium chloride at 298 K has been determined at different concentrations and the results are given below:
| Concentration/M | 0.001 | 0.010 | 0.020 | 0.050 | 0.100 |
| 102 × κ/S m−1 | 1.237 | 11.85 | 23.15 | 55.53 | 106.74 |
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Write mathematical expression of molar conductivity of the given solution at infinite dilution.
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(i) Predict the nature of electrolytes A and B.
(ii) What happens on extrapolation of ∧m to concentration approaching zero for electrolytes A and B?
Conductivity always decreases with decrease in concentration both, for weak and strong electrolytes because of the fact that ____________.
\[\ce{\Lambda^0_m(NH4OH)}\] is equal to ______.
When acidulated water (dil.H2SO4 solution) is electrolysed, will the pH of the solution be affected? Justify your answer.
Why on dilution the m Λm of \[\ce{CH3COOH}\] increases very fast, while that of \[\ce{CH3COONa}\] increases gradually?
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The molar conductivity of CH3COOH at infinite dilution is 390 Scm2/mol. Using the graph and given information, the molar conductivity of CH3COOK will be:
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