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A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
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With reference to structural variability and chemical reactivity, write the differences between lanthanoids and actinoids
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Give the structures of A, B and C in the following reaction:

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Explain the following term with a suitable example:
F-centres
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If NaCl is doped with 10−3 mol % of SrCl2, what is the concentration of cation vacancies?
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Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
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At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
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Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.
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Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
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What is the difference between multimolecular and macromolecular colloids? Give one example of each. How are associated colloids different from these two types of colloids?
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What are micelles? Give an example of a micellers system.
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Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element.
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Compare the chemistry of the actinoids with that of lanthanoids with reference to electronic configuration
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Compare the chemistry of the actinoids with that of lanthanoids with reference to oxidation states
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Compare the chemistry of the actinoids with that of lanthanoids with reference to chemical reactivity.
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Discuss briefly, giving an example in the given case and the role of coordination compounds in medicinal chemistry.
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CH3CO2H or CH2FCO2H
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Which acid of the pair shown here would you expect to be stronger?
CH2FCO2H or CH2ClCO2H
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Which acid of the pair shown here would you expect to be stronger?
CH2FCH2CH2CO2H or CH3CHFCH2CO2H
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Which acid of the pair shown here would you expect to be stronger?

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