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Predict which of the following will be coloured in the aqueous solution?
Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.
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Compare the stability of +2 oxidation state for the elements of the first transition series.
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How would you account for the following:
Of the d4 species, Cr2+ is strongly reducing while manganese (III) is strongly oxidising.
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How would you account for the following:
Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.
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How would you account for the following:
The d1 configuration is very unstable in ions.
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What is meant by ‘disproportionation’?
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Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?
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Calculate the number of unpaired electrons in the following gaseous ions:
Mn3+, Cr3+, V3+ and Ti3+. Which one of these is the most stable in an aqueous solution?
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What are alloys?
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What are inner transition elements?
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Use Hund’s rule to derive the electronic configuration of Ce3+ ion and calculate its magnetic moment on the basis of ‘spin-only’ formula.
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Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:
Electronic configurations
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Write down the number of 3d electrons in the following ion:
Cu2+
Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).
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Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.
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What can be inferred from the magnetic moment value of the following complex species?
| Example | Magnetic Moment (BM) |
| K2[MnCl4] | 5.9 |
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What is meant by the chelate effect?
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Classify the following as addition and condensation polymers: Terylene, Bakelite, Polyvinyl chloride, Polythene.
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Explain the difference between Buna-N and Buna-S
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Distinguish between the terms homopolymer and copolymer and give an example of each.
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How do you explain the functionality of a monomer?
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