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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Assertion: N, N-Diethylbenzene sulphonamide is insoluble in alkali.

Reason: Sulphonyl group attached to nitrogen atom is strong electron-withdrawing group.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Which of the following polymer is biodegradable?

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

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Which of the following polymer can be formed by using the following monomer unit?

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Which of the following monomers form biodegradable polymers?

(i) 3-hydroxybutanoic acid + 3-hydroxypentanoic acid

(ii) Glycine + amino caproic acid

(iii) Ethylene glycol + phthalic acid

(iv) Caprolactum

[15] Polymers
Chapter: [15] Polymers
Concept: undefined >> undefined

Give reasons to support the answer:

Presence of Alpha hydrogen in aldehydes and ketones is essential for aldol condensation.

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Cross aldol condensation occurs between

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Give reason for the following:

During the electrophilic substitution reaction of haloarenes, para-substituted derivative is the major product.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Name the suitable alcohol and reagent, from which 2-Chloro-2-methyl propane can be prepared.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Write the equations for the following reaction:

Tert butyl chloride is treated with sodium ethoxide.

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Give reasons for the following observation:

Aniline is acetylated before nitration reaction.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Give reasons for the following observation:

Aniline does not react with methyl chloride in the presence of anhydrous AlCl3 catalyst.

[9] Amines
Chapter: [9] Amines
Concept: undefined >> undefined

Write the reaction occurring at anode and cathode and the products of electrolysis of aq KCl.

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined

Convert the following:

Acetaldehyde to But-2-enal

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Predict the reagent for carrying out the following transformations:

Ethanal to 3-hydroxy butanal

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Which of the following reactions are feasible?

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Which of the following does not give aldol condensation reaction?

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Write the mechanism of the following reaction:

\[\ce{2CH3CH2OH ->[H^+][413 K] CH3-CH2-O-CH2-CH3 + H2O}\]

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
Concept: undefined >> undefined

Assertion (A): Chlorobenzene is resistant to electrophilic substitution reaction.

Reason (R): C-Cl bond in chlorobenzene acquires partial double bond characters due to resonance.

[6] Haloalkanes and Haloarenes
Chapter: [6] Haloalkanes and Haloarenes
Concept: undefined >> undefined

Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
Concept: undefined >> undefined

Four half-reactions, I to IV are shown below:

  1. \[\ce{2Cl^- -> Cl2 + 2e^-}\]
  2. \[\ce{4OH^- -> O2 + 2H2O + 2e^-}\]
  3. \[\ce{Na^+ + e^- -> Na}\]
  4. \[\ce{2H^+ + 2e^- -> H2}\]

Which two of these reactions are most likely to occur when concentrated brine is electrolysed?

[2] Electrochemistry
Chapter: [2] Electrochemistry
Concept: undefined >> undefined
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