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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Explain the solubility rule “like dissolves like” in terms of intermolecular forces that exist in solutions.

[1] Solutions
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What is the significance of Henry’s Law constant KH?

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Explain the following phenomena with the help of Henry’s law.

Painful condition known as bends.

[1] Solutions
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Match the items given in Column I with the type of solutions given in Column II.

Column I Column II
(i) Soda water (a) A solution of gas in solid
(ii) Sugar solution (b) A solution of gas in gas
(iii) German silver (c) A solution of solid in liquid
(iv) Air (d) A solution of solid in solid
(v) Hydrogen gas in palladium (e) A solution of gas in liquid
  (f) A solution of liquid in solid
[1] Solutions
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Can `E_(Cell)^Θ` or `∆_rG^Θ` for cell reaction ever be equal to zero?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Under what condition is ECell = 0 or ∆rG = 0?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Unlike dry cell, the mercury cell has a constant cell potential throughout its useful life. Why?

[2] Electrochemistry
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Write the Nernst equation for the cell reaction in the Daniel cell. How will the ECell be affected when concentration of Zn2+ ions is increased?

[2] Electrochemistry
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Assertion: Current stops flowing when ECell = 0.

Reason: Equilibrium of the cell reaction is attained.

[2] Electrochemistry
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Consider figure and answer the question to given below.

  1. Redraw the diagram to show the direction of electron flow.
  2. Is silver plate the anode or cathode?
  3. What will happen if salt bridge is removed?
  4. When will the cell stop functioning?
  5. How will concentration of Zn2+ ions and Ag+ ions be affected when the cell functions?
  6. How will the concentration of Zn2+ ions and Ag+ ions be affected after the cell becomes ‘dead’?
[2] Electrochemistry
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Extent of adsorption of adsorbate from solution phase increases with ______.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Which of the following phenomenon is applicable to the process shown in the figure?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Common impurities present in bauxite are:

(i) \[\ce{CuO}\]

(ii) \[\ce{ZnO}\]

(iii) \[\ce{Fe2O3}\]

(iv) \[\ce{SiO2}\] 

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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Which of the following elements does not show allotropy?

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Which of the following is correct for P4 molecule of white phosphorus?

(i) It has 6 lone pairs of electrons.

(ii) It has six P–P single bonds.

(iii) It has three P–P single bonds.

(iv) It has four lone pairs of electrons.

[7] P - Block Elements
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Which of the following statements are correct?

(i) All the three N – O bond lengths in \[\ce{HNO3}\] are equal.

(ii) All P – Cl bond lengths in \[\ce{PCl5}\] molecule in gaseous state are equal.

(iii) \[\ce{P4}\] molecule in white phosphorus have angular strain therefore white phosphorus is very reactive.

(iv) \[\ce{PCl}\] is ionic in solid state in which cation is tetrahedral and anion is octahedral.

[7] P - Block Elements
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Phosphorus has three allotropic forms — (i) white phosphorus (ii) red phosphorus and (iii) black phosphorus. Write the difference between white and red phosphorus on the basis of their structure and reactivity.

[7] P - Block Elements
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Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?

[4] d-block and f-block Elements
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General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)

[4] d-block and f-block Elements
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Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?

(i) \[\ce{Ce}\]

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

(iv) \[\ce{Ho}\]

[4] d-block and f-block Elements
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