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Distinguish Between: CH3COOH and HCOOH

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Question

Distinguish between: CH3COOH and HCOOH

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Solution

Formic acid gives the silver mirror test on treating with ammoniacal silver nitrate. Acetic acid does not give this test.

HCOOH + 2[Ag (NH3)2] NO3 →2Ag + CO2 + 2NH4NO3 + 2NH3

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2015-2016 (March) All India Set 2 C

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