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Give reasons: Lakes freeze from top towards bottom.
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Give reasons: Ice floats on water.
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\[\ce{H2O2}\] is a better oxidising agent than water. Explain.
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Melting point, enthalpy of vapourisation and viscosity data of \[\ce{H2O}\] and \[\ce{D2O}\] is given below :
| \[\ce{H, O}\] | \[\ce{D2O}\] | |
| Melting point / K | 373.0 | 374.4 |
| Enthalpy of vapourisation at (373 K)/kJ mol–1 | 40.66 | 41.61 |
| Viscosity/centipoise | 0.8903 | 1.107 |
On the basis of this data explain in which of these liquids intermolecular forces are stronger?
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Explain why \[\ce{HCl}\] is a gas and \[\ce{HF}\] is a liquid.
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Why does water show high boiling point as compared to hydrogen sulphide? Give reasons for your answer.
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How will you account for 104.5° bond angle in water?
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Write two reactions to explain amphoteric nature of water.
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Which of the following are the correct reasons for anomalous behaviour of lithium?
(i) Exceptionally small size of its atom.
(ii) Its high polarising power.
(iii) It has high degree of hydration.
(iv) Exceptionally low ionisation enthalpy.
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Write the general outer electronic configuration of f- block elements.
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What is Kc for the following equilibrium when the equilibrium concentration of each substance is: [SO2] = 0.60 M, [O2] = 0.82 M and [SO3] = 1.90 M?
\[\ce{2SO2(g) + O2(g) ⇌ 2SO3(g)}\]
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Write the expression for the equilibrium constant, Kc for each of the following reactions:
\[\ce{2NOCl (g) ⇌ 2NO (g) + Cl2 (g)}\]
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Write the expression for the equilibrium constant, Kc for the following reactions:
\[\ce{2Cu(NO3)2 (s) ⇌ 2CuO (s) + 4NO2 (g) + O2 (g)}\]
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Write the expression for the equilibrium constant, Kc for the following reactions:
\[\ce{CH3COOC2H5(aq) + H2O(l) ⇌CH3COOH (aq) + C2H5OH (aq)}\]
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Write the expression for the equilibrium constant, Kc for following reactions:
\[\ce{Fe^{3+}(aq) + 3OH^-(aq) ⇌ Fe(OH)3(s)}\]
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Write the expression for the equilibrium constant, Kc for the following reactions
\[\ce{I2 (s) + 5F2 ⇌ 2IF5}\]
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A reaction between N2 and O2 takes place as follows:
\[\ce{2N2 (g) + O2 (g) ⇌ 2N2O (g)}\]
If a mixture of 0.482 mol of N2 and 0.933 mol of O2 is placed in a 10 L reaction vessel and allowed to form N2O at a temperature for which Kc = 2.0 × 10-37, determine the composition of equilibrium mixture.
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Nitric oxide reacts with Br2 and gives nitrosyl bromide as per reaction given below:
\[\ce{2NO(g) + Br2 (g) ⇌ 2NOBr (g)}\]
When 0.087 mol of NO and 0.0437 mol of Br2 are mixed in a closed container at the constant temperature, 0.0518 mol of NOBr is obtained at equilibrium. Calculate the equilibrium amount of NO and Br2.
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One mole of H2O and one mole of CO are taken in 10 L vessel and heated to 725 K. At equilibrium, 40% of water (by mass) reacts with CO according to the equation,
\[\ce{H2O (g) + CO (g) ⇌ H2 (g) + CO2 (g)}\]
Calculate the equilibrium constant for the reaction.
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At 700 K, the equilibrium constant for the reaction
\[\ce{H_{2(g)} + I_{2(g)} ↔ 2HI_{(g)}}\]
is 54.8. If 0.5 molL–1 of HI(g) is present at equilibrium at 700 K, what are the concentration of H2(g) and I2(g) assuming that we initially started with HI(g) and allowed it to reach equilibrium at 700 K?
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