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Karnataka Board PUCPUC Science Class 11

Explain why HCl is a gas and HF is a liquid.

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Question

Explain why \[\ce{HCl}\] is a gas and \[\ce{HF}\] is a liquid.

Short/Brief Note
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Solution

Due to greater electronegativity of \[\ce{F}\] over \[\ce{Cl, F}\] forms stronger \[\ce{H}\] – bonds as compared to \[\ce{Cl}\]. As a result, more energy is needed to break the \[\ce{H}\] – bonds in \[\ce{HF}\] than in \[\ce{HCl}\] and hence the b.p. of \[\ce{HF}\] is higher than that of \[\ce{HCl}\]. Consequently, \[\ce{H - F}\] is liquid while \[\ce{HCl}\] is a gas at room temperature.

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Physical Properties of Water
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Chapter 9: Hydrogen - Multiple Choice Questions (Type - I) [Page 119]

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NCERT Exemplar Chemistry Exemplar [English] Class 11
Chapter 9 Hydrogen
Multiple Choice Questions (Type - I) | Q 43 | Page 119

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