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Science (English Medium) Class 12 - CBSE Important Questions for Chemistry

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Account for the following:

Glucose is a reducing sugar

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Classification of Carbohydrates

Account for the following:

What happens when D – glucose is treated with the following reagents

Bromine water

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Carbohydrates >> Structures of Glucose

Account for the following:

What happens when D – glucose is treated with the following reagents

HNO3

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Carbohydrates >> Structures of Glucose

Read the passage carefully and answer the questions that follow:

Strengthening the Foundation: Chargaff Formulates His "Rules"

Many people believe that James Watson and Francis Crick discovered DNA in the 1950s. In reality, this is not the case. Rather, DNA was first identified in the late 1860s by Swiss chemist Friedrich Miescher. Then, in the decades following Miescher's discovery, other scientists- notably, Phoebus Levene and Erwin Chargaff- carried out a series of research efforts that revealed additional details about the DNA molecule, including its primary chemical components and the ways in which they joined with one another. Without the scientific foundation provided by these pioneers, Watson and Crick may never have reached their groundbreaking conclusion of 1953: that the DNA molecule exists in the form of a three-dimensional double helix.
Chargaff, an Austrian biochemist, as his first step in this DNA research, set out to see whether there were any differences in DNA among different species. After developing a new paper chromatography method for separating and identifying small amounts of organic material, Chargaff reached two major conclusions:
(i) the nucleotide composition of DNA varies among species.
(ii) Almost all DNA, no matter what organism or tissue type it comes from maintains certain properties, even as its composition varies. In particular, the amount of adenine (A) is similar to the amount of thymine (T), and the amount of guanine (G) approximates the amount of cytosine (C). In other words, the total amount of purines (A + G) and the total amount of pyrimidines (C + T) are usually nearly equal. This conclusion is now known as "Chargaff's rule."
Chargaff’s rule is not obeyed in some viruses. These either have single-stranded DNA or RNA as their genetic material.

Answer the following questions:

  1. A segment of DNA has 100 adenine and 150 cytosine bases. What is the total number of nucleotides present in this segment of DNA?
  2. A sample of hair and blood was found at two sites. Scientists claim that the samples belong to same species. How did the scientists arrive at this conclusion?
  3. The sample of a virus was tested and it was found to contain 20% adenine, 20% thymine, 20% guanine and the rest cytosine. Is the genetic material of this virus (a) DNA-double helix (b) DNA-single helix (c) RNA? What do you infer from this data?
    OR
    How can Chargaff’s rule be used to infer that the genetic material of an organism is double-helix or single-helix?
Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Nucleic Acids >> Structure of Nucleic Acids

Why tryptophan is an essential amino acid?

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Proteins >> Amino Acids

An α-helix is a structural feature of ______.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Proteins >> Structure of Proteins

Proteins are polymers of ______.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Proteins >> Structure of Proteins

When D-glucose reacts with HI, it forms ______.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Carbohydrates >> Structures of Glucose

Mention two important functions of nucleic acids.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Introduction of Nucleic Acids

Assertion (A): Proteins are polymers of α-amino acids connected by a peptide bond.

Reason (R): A tetrapeptide contains 4 amino acids linked by 4 peptide bonds.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Proteins >> Structure of Proteins

Which of the following statements is not true about glucose?

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Carbohydrates >> Preparation of Glucose

Assertion (A): Vitamin C cannot be stored in our body.

Reason (R): Vitamin C is fat soluble and is excreted from the body in urine.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Vitamins >> Classification of Vitamins

β-pleated sheet structure in proteins refers to ______.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Proteins >> Structure of Proteins

Assertion (A): The backbone of DNA and RNA molecules is a chain consisting of heterocyclic base, pentose sugar and phosphate group.

Reason (R): Nucleotides and nucleosides mainly differ from each other in the presence of phosphate group.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Introduction of Nucleic Acids

The vitamins which can be stored in our body are ______.

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Vitamins >> Classification of Vitamins

Assertion: Enzymes are very specific for a particular reaction and for a particular substrate.

Reason: Enzymes are biocatalysts.

Select the most appropriate answer from the options given below:

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Introduction of Enzymes

DNA fingerprinting is used to determine paternity of an individual. Which property of DNA helps in the procedure?

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Nucleic Acids >> Structure of Nucleic Acids

What structural change will occur when a native protein is subjected to change in pH?

Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Proteins >> Denaturation of Proteins

When sucrose is hydrolysed the optical rotation values are measured using a polarimeter and are given in the following table:

S. No. Time (hours) Specific Rotation
1 0 + 66.5°
2 - 39.9°
  1. Account for the two specific rotation values.
  2. What is the specific name given to sucrose based on the above observation?
  3. One of the products formed during the hydrolysis of sucrose is a glucose, that reacts with hydroxylamine to give compound A. Identify compound A.
Appears in 1 question paper
Chapter: [10] Biomolecules
Concept: Biomolecules in the Cell > Carbohydrates >> Disaccharides - Sucrose, Maltose and Lactose

Which of the following is a natural polymer ? Buna-S, Proteins, PVC

Appears in 1 question paper
Chapter: [15] Polymers
Concept: Types of Polymerisation Reactions - Addition Polymerisation or Chain Growth Polymerisation
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