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Complete the following:
\[\ce{C6H5NO2 ->[Sn/HCl] A ->[Br2/H2O] B ->[NaNO2/HCl][273 - 278 K] C ->[HBF4][Δ] D}\]
Concept: Acids >> Nomenclature of Carboxylic Acids
Which of the following tests/reactions is given by aldehydes as well as ketones?
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Oxidation
The oxidation of toluene to benzaldehyde by chromyl chloride is called ______.
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Preparation of Aldehydes
Write the reaction and IUPAC name of the product formed when 2-Methylpropanal (isobutyraldehyde) is treated with ethyl magnesium bromide followed by hydrolysis.
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Nomenclature of Aldehydes and Ketones
Write the equations for the following reaction:
Salicylic acid is treated with acetic anhydride in the presence of conc H2SO4
Concept: Acids >> Chemical Reactions of Carboxylic Acids - Reactions Involving Cleavege of C-OH Bond
A hydrocarbon (A) with molecular formula C5H10 on ozonolysis gives two products (B) and (C). Both (B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (B) give a silver mirror on reaction with Tollen’s reagent.
- Identify (A), (B) and (C).
- Write the reaction of B with Tollen’s reagent.
- Write the equation for iodoform test for C.
- Write down the equation for aldol condensation reaction of B and C.
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Oxidation
Arrange the following in the increasing order of their property indicated:
Ethanal, Propanone, Propanal, Butanone (reactivity towards nucleophilic addition)
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Nucleophilic Addition Reactions
Write the IUPAC name of the following complex:
K2[PdCl4]
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Nomenclature of Aldehydes and Ketones
Explain the following reactions:
Clemmensen reaction
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Reduction
Explain the following reactions:
Stephan reaction
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Preparation of Aldehydes
Write the IUPAC name of the following complex:
[Pt(NH3)6]Cl4
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Nomenclature of Aldehydes and Ketones
Using IUPAC norms, write the formula for the following:
Pentaamminenitrito-N-Cobalt (III)
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Nomenclature of Aldehydes and Ketones
Using IUPAC norms write the formula for the following:
Tetrahydroxidozincate (II)
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Nomenclature of Aldehydes and Ketones
Predict the reagent for carrying out the following transformations:
Benzoyl chloride to Benzaldehyde
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Preparation of Aldehydes
Predict the reagent for carrying out the following transformations:
Ethanal to 3-hydroxy butanal
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Reactions Due to α-hydrogen
Which of the following does not give aldol condensation reaction?
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Reactions Due to α-hydrogen
Which of the following does not give Cannizzaro reaction?
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Other Reactions
Aldehydes and ketones react with hydroxylamine to form ______.
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Nucleophilic Addition Reactions
The reagent that can be used to distinguish acetophenone and benzophenone is ______.
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Oxidation
Which of the following compounds will undergo self-condensation in the presence of dilute NaOH solution?
Concept: Concepts of Aldehydes, Ketones, and Carboxylic Acids >> Chemical Reactions of Aldehydes and Ketones - Reactions Due to α-hydrogen
