- Strong alkalis (e.g., NaOH, KOH) dissociate almost completely in water, producing a high concentration of OH⁻ ions.
- Weak alkalis (e.g., NH₄OH, Ca(OH)₂) dissociate only partially in water, giving fewer OH⁻ ions.
- Acidity of a base is the number of OH⁻ ions it can produce per molecule in aqueous solution.
- Monoacidic bases (NaOH, KOH, NH₄OH) produce one OH⁻ ion per molecule.
- Diacidic and triacidic bases produce two [Ca(OH)₂] and three [Al(OH)₃, Fe(OH)₃] OH⁻ ions respectively per molecule.
Definitions [8]
Definition: Acid
Acids are defined as compounds which contain one or more hydrogen atoms and when dissolved in water, produce hydronium ions (H3O+) the only positively charged ions.
Define Acid.
An acid is a compound which when dissolved in water produces hydronium ion(H3O+), the only positively charged
ion and a negative ion.
Define the term ‘basicity’ of an acid.
The basicity of an acid is defined as the number of hydronium ions (H3O+) that can be produced by the ionization of one molecule of that acid in aqueous solution.
Definition: Bases
A base is either a metallic oxide or a metallic hydroxide or ammonium hydroxide which reacts with hydronium ions of an acid to form a salt and water only.
Definition: Alkali
An alkali is a basic hydroxide which when dissolved in water produces hydroxyl (OH-) ions as the only negatively charged ions.
Define ionisation.
Ionization is the condition of being dissociated into ions by heat or radiation or chemical reactions or electrical discharge.
Definition: Universal Indicator
The universal indicator, is a mixture of indicator dyes that gives a spectrum of colours depending on how acidic or alkaline a solution is. Universal indicators give different colours at different concentrations of hydrogen ions in a solution.
Definition: pH of Solution
The pH of a solution is the negative logarithm to the base 10 of the hydrogen ion concentration expressed in moles per litre.
Key Points
Key Points: Classification of Acids
- Organic acids come from plants, contain carbon, and are usually weak.
- Inorganic acids come from minerals, don’t have carbon (mostly), and are strong.
- Monobasic, dibasic, and tribasic acids give 1, 2, or 3 H₃O⁺ ions per molecule.
- Oxyacids have oxygen (like H₂SO₄); hydracids don’t (like HCl).
- Acid strength depends on ionisation; concentration means how much acid is in water.
Key Points: Preparation of Acids
- By Synthesis: Acids like HCl are made by combining hydrogen with non-metals.
- From Acidic Oxides: Acidic oxides + water → acids (e.g. CO₂ + H₂O → H₂CO₃).
- By Oxidation: Sulphur or phosphorus + HNO₃ → H₂SO₄ or H₃PO₄.
- By Displacement: Strong acid (like H₂SO₄) displaces weaker acids (like HCl) from their salts.
Key Points: Physical Properties of Acids
- Taste & Safety: Acids taste sour; mineral acids are corrosive and should never be tasted.
- Physical State: Acids can be solids (e.g., boric acid) or liquids (e.g., HCl, H₂SO₄); some are volatile, others are not.
- Skin Effect: Strong acids cause burns; conc. H₂SO₄ chars skin, HNO₃ turns it yellow, HCl gives amber color.
- Indicators: Acids turn blue litmus red; also change colors of methyl orange and red cabbage extract.
- Conductivity: Acids conduct electricity in aqueous solutions, acting as electrolytes.
Key Points: Chemical Properties of Acids
- Acids + Metals → Salt + Hydrogen gas (H₂).
- Acids + Bases → Salt + Water (Neutralisation).
- Acids + Carbonates → CO₂ gas is released.
- Acids + Sulphites → SO₂ gas is released.
- Acids + Sulphides → H₂S gas is released.
Key Points: Classification of Bases
Key Points: Physical Properties of Bases
Key Points: Chemical Properties of Bases
- Carbon Dioxide Absorption: Strong alkalis like NaOH and KOH absorb CO₂ from the air to form carbonates and water.
- Neutralisation: Bases neutralise acids to form salt and water (e.g., Ca(OH)₂ + HCl → CaCl₂ + H₂O).
- Precipitation of Hydroxides: Bases form insoluble hydroxides with salts of heavy metals like Cu, Fe, and Zn.
- Amphoteric Hydroxides: Hydroxides of Zn, Al, and Pb dissolve in excess NaOH/KOH, forming soluble salts.
- Ammonia Release: Alkalies release ammonia gas when heated with ammonium salts (e.g., NH₄Cl + NaOH → NH₃).
Key Points: Importance of pH in Everyday Life
| S.No. | Area of Life | Role of pH |
|---|---|---|
| 1. | Human Body | Functions within pH range 7.0 – 7.8; imbalance can affect survival. |
| 2. | Agriculture |
Crops grow best in a specific pH:
|
| 3. | Acid Rain | Rainwater with pH < 5.6 contains acids (H₂SO₄, HNO₃, H₂CO₃) from pollutants; these harm soil, marine life, and monuments. |
| 4. | Medicine | Diseases are diagnosed by checking blood and urine pH. |
| 5. | Digestive System | Excess HCl lowers pH, causing pain; antacids like Mg(OH)₂ neutralise it. |
| 6. | Tooth Decay | pH < 5.5 corrodes tooth enamel; toothpaste neutralizes mouth acids. |
| 7. | Bee Sting | Injects acid into the skin; baking soda (a base) neutralises the sting. |
Important Questions [6]
- Write a Balanced Chemical Equation for the Reaction of Sodium Hydroxide Solution with Iron (Iii) Chloride Solution
- Three Solutions P, Q and R Have Ph Value of 3.5, 5.2 and 12.2 Respectively. Which One of These is A: Weak Acid? and Strong Alkali?
- State One Observation for Each of the Following : a Small Piece of Zinc is Added to Dilute Hydrochloric Acid
- Give the Appropriate Term Defined by the Statements Given Below : the Substance that Releases Hydronium Ion as the Only Positive Ion When Dissolved in Water.
- Name the Particles Present in : Weak Electrolyte
- The metal that will not produce hydrogen gas when reacted with dilute acids.
Concepts [15]
- Basics of Acids, Bases, and Salts
- Acids
- Classification of Acids
- Preparation of Acids
- Properties of Acids > Physical Properties
- Properties of Acids > Chemical Properties
- Uses of Acids
- Bases (Alkalis)
- Classification of Bases (Alkalis)
- Preparation of Bases
- Properties of Bases > Physical Properties
- Properties of Bases > Chemical Properties
- Uses of Bases
- Test for Acidity and Alkalinity
- Importance of pH in Everyday Life
