Advertisements
Advertisements
Question
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2CH2OH + SOCl2 ->}\]
Advertisements
Solution
\[\ce{\underset{Propan-1-ol}{CH3CH2CH2OH} + SOCl2 ->[nucleophilic substitution] \underset{1-Chloropropane}{CH3CH2CH2Cl} + HCl\uparrow + SO2\uparrow}\]
APPEARS IN
RELATED QUESTIONS
Write the isomers of the compound having the formula C4H9Br.
Write the mechanism of the following reaction:
\[\ce{{n}BuBr + KCN ->[EtOH-H2O] {n}BuCN}\]
What happens when ethyl chloride is treated with aqueous KOH?
What is the action of the following on ethyl bromide:
moist silver oxide
Most reactive halide towards SN1 reaction is ____________.
Which of the following is an optically active compound?
Among the following, the dissociation constant is highest for:
The increasing order of nucleophilicity would be:
Which of the following compounds will give a racemic mixture on nucleophilic substitution by OH ion?
1-Bromoethane, 1-Bromopropane, 1-Bromobutane, Bromobenzene
Which reagent will you use for the following reaction?
\[\ce{CH3CH2CH2CH3 -> CH3CH2CH2CH2Cl + CH3CH2CHClCH3}\]
Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.
(i) Both the compounds form same product on treatment with alcoholic KOH.
(ii) Both the compounds form same product on treatment with aq.NaOH.
(iii) Both the compounds form same product on reduction.
(iv) Both the compounds are optically active.
Cyanide ion acts as an ambident nucleophile. From which end it acts as a stronger nucleophile in aqueous medium? Give reason for your answer.
The number of chiral alcohol (s) with molecular formula C4H10O is ______.
The major product formed in the following reaction is:

In SN1 reactions, the correct order of reactivity for the following compounds:
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is ______.
An organic compound A with the molecular formula (+) C4H9Br undergoes hydrolysis to form (+) C4H9OH. Give the structure of A and write the mechanism of the reaction.
Discuss SN2 mechanism of methyl bromide using aqueous KOH.
Explain why Grignard reagents should be prepared under anhydrous conditions.
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\\phantom{...}|\\\phantom{....}\ce{Br}\end{array}\] or \[\begin{array}{cc}\phantom{.....}\ce{CH3}\\\phantom{..}|\\\ce{H3C - C - Br}\\\phantom{..}|\\\phantom{....}\ce{CH3}\end{array}\]
